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Aminopropyl-grafted various silica mesostructures for adsorption of molybdenum ions from Re-containing effluent

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Abstract

Four different silica mesostructures, SBA-15 with mesopore size (8.5 nm), SBA-15 with mesopore size (10.3 nm), mesocellular foam (MCF) with uniform cell size (33.2 nm), and MCF with bimodal mesoporosity, were grafted with aminopropyl groups and used for selective recovery of Mo(VI) from Re(VII)-containing effluent. Adsorption isotherms and mechanism of Mo(VI) adsorption on these materials were studied. The adsorbed complexes of Mo(VI) could be formed by ion exchange process or/and by chelation reaction. This study shows a new approach for fractional recovery and separation of Mo(VI) from Re(VII) by using amino-modified SBA-15-type mesoporous silica.

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Acknowledgments

This project is supported by National Natural Science Foundation of China (21201030, 51272039), Scientific Research Found of Liaoning Provincial Education Department (L2014004), Fundamental Research Funds for Central Universities (N141005001, N130810003), and Program for Liaoning Excellent Talents in University (LR2015026).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Northeastern University, Shenyang, China

    Weijun Shan, Wei Wang & Hongqiang Ru

  2. College of Chemistry, Liaoning University, Shenyang, 110036, China

    Weijun Shan, Qing Zhang, Yanning Shu & Ying Xiong

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  1. Weijun Shan
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  2. Qing Zhang
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  3. Yanning Shu
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  4. Wei Wang
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  5. Hongqiang Ru
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  6. Ying Xiong
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Correspondence to Hongqiang Ru or Ying Xiong.

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Shan, W., Zhang, Q., Shu, Y. et al. Aminopropyl-grafted various silica mesostructures for adsorption of molybdenum ions from Re-containing effluent. Adsorption 22, 859–869 (2016). https://doi.org/10.1007/s10450-016-9777-x

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  • DOI: https://doi.org/10.1007/s10450-016-9777-x

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