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Simultaneous Analysis of Organophosphorus Pesticides in Water by Magnetic Solid-Phase Extraction Coupled with GC–MS

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Abstract

Magnetic solid-phase extraction (MSPE) coupled with gas chromatography–mass spectrometry was applied for the analysis of organophosphorus pesticides (OPPs) in water samples. We chose C18-functionalized Fe3O4@mSiO2 microspheres as the magnetic sorbents to extract and enrich OPPs from water samples with the advantages of good solubility in water, large surface area and fast separation ability. In this study, six kinds of OPPs were analyzed and various parameters of MSPE procedure, including eluting solvent, the amount of magnetic absorbents and extraction time were optimized. Validation experiments showed that the optimized method had good linearity with correlation coefficients r 2 > 0.98 and satisfactory precision with the relative standard deviation ≤10.7 %. The limits of detection were 1.8–5.0 μg L−1 and the limits of quantification ranged from 6.1 to 16.7 μg L−1. We concluded that the proposed method was successfully applied to analyze OPPs in real water samples and the results indicated that it had the advantages of simplicity, convenience and efficiency.

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Authors and Affiliations

  1. Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People’s Republic of China

    Jia Xie, Tianshun Liu, Guoxin Song & Yaoming Hu

  2. Department of Chemistry, Fudan University, Shanghai, 200433, People’s Republic of China

    Chunhui Deng

Authors
  1. Jia Xie
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  2. Tianshun Liu
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  3. Guoxin Song
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  4. Yaoming Hu
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  5. Chunhui Deng
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Correspondence to Guoxin Song or Yaoming Hu.

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Xie, J., Liu, T., Song, G. et al. Simultaneous Analysis of Organophosphorus Pesticides in Water by Magnetic Solid-Phase Extraction Coupled with GC–MS. Chromatographia 76, 535–540 (2013). https://doi.org/10.1007/s10337-013-2408-8

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  • DOI: https://doi.org/10.1007/s10337-013-2408-8

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