Abstract
Hydrothermally synthesized Co3O4 microspheres were anchored to graphite oxide (GO) and thermally reduced graphene oxide (rGO) composites at different cobalt weight percentages (1, 10, and 100 wt%). The composite materials served as the active materials in bulk electrodes for two-electrode cell electrochemical capacitors (ECCs). GO/Co3O4–1 exhibited a high energy density of 35 W kg−1 with a specific capacitance (C sp) of 196 F g−1 at a maximum charge density of 1 A g−1. rGO/Co3O4-100 presented high specific power output values of up to 23.41 kW h kg−1 with linear energy density behavior for the charge densities applied between 0.03 and 1 A g−1. The composite materials showed Coulombic efficiencies of 96 and 93 % for GO/Co3O4–1 and rGO/Co3O4–100 respectively. The enhancement of capacitive performance is attributed to the oxygenated groups in the GO ECC and the specific area in the rGO ECC. These results offer an interesting insight into the type of carbonaceous support used for graphene derivative electrode materials in ECCs together with Co3O4 loading to improve capacitance performance in terms of specific energy density and specific power.
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Pandolfo AG, Hollenkamp AF (2006) Carbon properties and their role in supercapacitors. J Power Sources 157(1):11–27
Conway BE (1999) Electrochemical supercapacitors : scientific fundamentals and technological applications. Springer, New York
Ghosh A, Lee YH (2012) Carbon-based electrochemical capacitors. ChemSusChem 5(3):480–499
Wang FX, Xiao SY, Hou YY, Hu CL, Liu LL, Wu YP (2013) Electrode materials for aqueous asymmetric supercapacitors. RSC Adv 3(32):13059–13084
Jeong GH, Baek S, Lee S, Kim SW (2016) Metal oxide/graphene composites for supercapacitive electrode materials. Chemistry-an Asian Journal 11(7):949–964
Xin Zhaoa HT, Zhub M (2009) Carbon nanosheets as the electrode material in supercapacitors. J Power Sources 194:1208–1212
Wang Y, Shi Z, Huang Y, Ma Y, Wang C, Chen M (2009) Supercapacitor devices based on graphene materials. J Phys Chem C 113(30):13103–13107
Thi Toan N, Van Hoa N, Deivasigamani RK, Kharismadewi D, Iwai Y, Shim J-J (2016) Facile synthesis of cobalt oxide/reduced graphene oxide composites for electrochemical capacitor and sensor applications. Solid State Sci 53:71–77
Kumar N, Yu Y-C, Lu YH, Tseng TY (2016) Fabrication of carbon nanotube/cobalt oxide nanocomposites via electrophoretic deposition for supercapacitor electrodes. J Mater Sci 51(5):2320–2329
Zhou F, Liu Q, Gu J, Zhang W, Zhang D (2015) A facile low-temperature synthesis of highly distributed and size-tunable cobalt oxide nanoparticles anchored on activated carbon for supercapacitors. J Power Sources 273:945–953
Das B, Behm M, Lindbergh G, Reddy MV, Chowdari BVR (2015) High performance metal nitrides, MN (M = Cr, Co) nanoparticles for non-aqueous hybrid supercapacitors. Adv Powder Technol 26(3):783–788
Krishnan SG, Reddy MV, Harilal M, Vidyadharan B, Misnon II, Rahim MHA, Ismail J, Jose R (2015) Characterization of MgCo2O4 as an electrode for high performance supercapacitors. Electrochim Acta 161:312–321
Aravindan V, Reddy MV, Madhavi S, Mhaisalkar SG, Subba Rao GV, Chowdari BVR (2011) Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode. J Power Sources 196(20):8850–8854
Li Z-Y, Bui PTM, Kwak D-H, Akhtar MS, Yang OB (2016) Enhanced electrochemical activity of low temperature solution process synthesized Co3O4 nanoparticles for pseudo-supercapacitors applications. Ceram Int 42(1, Part B):1879–1885
Zhang C, Xie L, Song W, Wang J, Sun G, Li K (2013) Electrochemical performance of asymmetric supercapacitor based on Co3O4/AC materials. J Electroanal Chem 706:1–6
Wang XW, Liu SQ, Wang HY, Tu FY, Fang D, Li YH (2012) Facile and green synthesis of Co3O4 nanoplates/graphene nanosheets composite for supercapacitor. J Solid State Electrochem 16(11):3593–3602
Dong C, Xiao X, Chen G, Guan H, Wang Y (2014) Hydrothermal synthesis of Co3O4 nanorods on nickel foil. Mater Lett 123:187–190
Hao Y, Wang H, Hu Z, Gan L, Xu Z (2015) Facile synthesis of mesoporous cobalt oxide rugby balls for electrochemical energy storage. New J Chem 39(1):68–71
Li Q, Hu X, Yang Q, Yan Z, Kang L, Lei Z, Yang Z, Liu Z (2014) Electrocapacitive performance of graphene/Co3O4 hybrid material prepared by a nanosheet assembly route. Electrochim Acta 119:184–191
Bianco A, Cheng H-M, Enoki T, Gogotsi Y, Hurt RH, Koratkar N, Kyotani T, Monthioux M, Park CR, Tascon JMD, Zhang J (2013) All in the graphene family—a recommended nomenclature for two-dimensional carbon materials. Carbon 65:1–6
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339
Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502
Subramanian V, Zhu H, Wei B (2006) Synthesis and electrochemical characterizations of amorphous manganese oxide and single walled carbon nanotube composites as supercapacitor electrode materials. Electrochem Commun 8(5):827–832
Kötz R, Carlen M (2000) Principles and applications of electrochemical capacitors. Electrochim Acta 45(15–16):2483–2498
Pei S, Cheng H-M (2012) The reduction of graphene oxide. Carbon 50(9):3210–3228
Dobiášová L, Starý V, Glogar P, Valvoda V (1999) Analysis of carbon fibers and carbon composites by asymmetric X-ray diffraction technique. Carbon 37(3):421–425
Kudin KN, Ozbas B, Schniepp HC, Prud'homme RK, Aksay IA, Car R (2008) Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett 8(1):36–41
Ferrari A, Meyer J, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov K, Roth S, Geim A (2006) Raman spectrum of graphene and graphene layers. Phys Rev Lett 97:187401
Chua CK, Sofer Z, Pumera M (2012) Graphite oxides: effects of permanganate and chlorate oxidants on the oxygen composition. Chem Eur J 18(42):13453–13459
Reddy MV, Beichen Z, Nicholette LJ, Kaimeng Z, Chowdari BVR (2011) Molten salt synthesis and its electrochemical characterization of Co3O4 for lithium batteries. Electrochem Solid-State Lett 14(5):A79–A82
Aghazadeh M, Barmi A-AM, Gharailou D, Peyrovi MH, Sabour B, Khosroshahi FN (2013) Cobalt hydroxide ultra-fine nanoparticles with excellent energy storage ability. Appl Surf Sci 283(0):871–875
Hadjiev VG, Iliev MN, Vergilov IV (1988) The Raman spectra of Co3O4. J Phys C Solid State Phys 21(7):L199
Blazsó M, Jakab E (1999) Effect of metals, metal oxides, and carboxylates on the thermal decomposition processes of poly (vinyl chloride). J Anal Appl Pyrolysis 49(1–2):125–143
Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39(1):228–240
Dong X-C, Xu H, Wang X-W, Huang Y-X, Chan-Park MB, Zhang H, Wang L-H, Huang W, Chen P (2012) 3D graphene–cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection. ACS Nano 6(4):3206–3213
Li J, Zhao W, Huang F, Manivannan A, Wu N (2011) Single-crystalline Ni(OH)2 and NiO nanoplatelet arrays as supercapacitor electrodes. Nanoscale 3(12):5103–5109
García-Gómez A, Duarte RG, Eugénio S, Silva TM, Carmezim MJ, Montemor MF (2015) Fabrication of electrochemically reduced graphene oxide/cobalt oxide composite for charge storage electrodes. J Electroanal Chem 755:151–157
Conway BE, Pell WG (2003) Double-layer and pseudocapacitance types of electrochemical capacitors and their applications to the development of hybrid devices. J Solid State Electrochem 7(9):637–644
Prabaharan SRS, Vimala R, Zainal Z (2006) Nanostructured mesoporous carbon as electrodes for supercapacitors. J Power Sources 161(1):730–736
Pacheco D, Smith M, Morales E (2011) Characterization of composite mesoporous carbon/conducting polymer electrodes prepared by chemical oxidation of gas-phase absorbed monomer for electrochemical capacitors. Int J Electrochem Sci 6(1):78–90
Li Y, Huang K, Liu S, Yao Z, Zhuang S (2011) Meso-macroporous Co3O4 electrode prepared by polystyrene spheres and carbowax templates for supercapacitors. J Solid State Electrochem 15(3):587–592
Reddy MV, Prithvi G, Loh KP, Chowdari BVR (2014) Li storage and impedance spectroscopy studies on Co3O4, CoO, and CoN for Li-ion batteries. ACS Appl Mater Interfaces 6(1):680–690
Di Fabio A, Giorgi A, Mastragostino M, Soavi F (2001) Carbon-poly(3-methylthiophene) hybrid supercapacitors. J Electrochem Soc 148(8):A845–A850
Acknowledgments
This work was supported by the Consejo Nacional de Ciencia y Tecnología (Mexico) CB 2011-166356 project fund. The authors would like to thank PRODEP for the support provided throughout the UQROO/DGIP/003/16 project; Consejo Nacional de Ciencia y Tecnología student grant (362308), and the CICY student exchange program. V.P., also acknowledges the technical support for characterization from M. Bass-López (CICY), I. Muñoz, J. Gómez, P. González, and E. Benito (ICTP).
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Parra-Elizondo, V., Escobar-Morales, B., Morales, E. et al. Effect of carbonaceous support between graphite oxide and reduced graphene oxide with anchored Co3O4 microspheres as electrode-active materials in a solid-state electrochemical capacitor. J Solid State Electrochem 21, 975–985 (2017). https://doi.org/10.1007/s10008-016-3439-5
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DOI: https://doi.org/10.1007/s10008-016-3439-5