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Local NMR Relaxation of Dendrimers in the Presence of Hydrodynamic Interactions

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Abstract

We study the role of hydrodynamic interactions for the relaxation of segments’ orientations in dendrimers. The dynamics is considered in the Zimm framework. It is shown that inclusion of correlations between segments’ orientations plays a major role for the segments’ mobility, which reveals itself in the nuclear magnetic resonance relaxation functions. The enhancement of the reorientation dynamics of segments due to the hydrodynamic interactions is more significant for the inner segments. This effect is clearly pronounced in the reduced spectral density \(\omega J(\omega )\), maximum of which shifts to higher frequencies when the hydrodynamic interactions are taken into account.

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Acknowledgements

M.D. acknowledges the support through Grant No. GRK 1642/1 of the Deutsche Forschungsgemeinschaft. D.A.M. acknowledges the Russian Foundation for Basic Research (project no. 14-03-00926) and the Government of the Russian Federation (project no. 074-U01).

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Authors and Affiliations

  1. Institute of Physics, University of Freiburg, Hermann-Herder-Str. 3, 79104, Freiburg, Germany

    Maxim Dolgushev & Sebastian Schnell

  2. Institut Charles Sadron, Université de Strasbourg and CNRS, 23 rue du Loess, 67034, Strasbourg Cedex, France

    Maxim Dolgushev

  3. St. Petersburg State University, 7/9 Universitetskaya nab., St. Petersburg, 199034, Russia

    Denis A. Markelov

  4. St. Petersburg National Research University of Information Technologies Mechanics and Optics (ITMO University), Kronverkskiy pr. 49, St. Petersburg, 197101, Russia

    Denis A. Markelov

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Correspondence to Maxim Dolgushev.

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Dolgushev, M., Schnell, S. & Markelov, D.A. Local NMR Relaxation of Dendrimers in the Presence of Hydrodynamic Interactions. Appl Magn Reson 48, 657–671 (2017). https://doi.org/10.1007/s00723-017-0897-6

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  • DOI: https://doi.org/10.1007/s00723-017-0897-6

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