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Structural Phase Transition of Perovskite-Type N(CH3)4CdBr3 Studied by MAS NMR and Static NMR

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Abstract

The structural geometry change in the perovskite-type N(CH3)4CdBr3 single crystal near the phase transition temperature of T C = 390 K was investigated using magic angle spinning nuclear magnetic resonance techniques. For 1H and 13C nuclei, the temperature dependences of their chemical shift, spectral intensity, and spin–lattice relaxation time (T 1ρ) in the rotating frame were obtained and analyzed. While the chemical shift and T 1ρ of 1H showed change near T C, those of 13C did not. In addition, the 113Cd spin–lattice relaxation time T 1 in the laboratory frame near T C show no evidence of anomalous change near the phase transition temperature, which coincides with the measured changes in the 1H T 1ρ. The driving force for this phase transition was connected to the 1H in the CH3 groups.

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Acknowledgements

This research was supported by the Basic Science Research program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education Science and Technology (2015R1A1A3A04001077 and 2016R1A6A1A03012069).

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Authors and Affiliations

  1. Analytical Laboratory of Advanced Ferroelectric Crystals, Jeonju University, Jeonju, 55069, South Korea

    Ae Ran Lim

  2. Department of Science Education, Jeonju University, Jeonju, 55069, South Korea

    Ae Ran Lim

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  1. Ae Ran Lim
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Correspondence to Ae Ran Lim.

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Lim, A.R. Structural Phase Transition of Perovskite-Type N(CH3)4CdBr3 Studied by MAS NMR and Static NMR. Appl Magn Reson 48, 297–305 (2017). https://doi.org/10.1007/s00723-017-0861-5

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  • DOI: https://doi.org/10.1007/s00723-017-0861-5

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