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Efficient and heterogeneous transfer hydrogenation of nitroarenes using immobilized palladium nanoparticles on silica–starch substrate (PNP-SSS)

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Abstract

This paper reports the efficient transfer hydrogenation of nitroarenes to anilines using immobilized palladium nanoparticles on a silica–starch substrate (PNP-SSS) in the presence of sodium borohydride as a reducing agent in water as a green solvent at room temperature. The prepared PNP-SSS nanocatalyst was characterized using FT-IR, XRD, SEM, EDS, BET, TEM, and ICP analyses. This catalyst system was found to be a powerful heterogeneous catalyst system to reduce the aromatic nitro compounds yielding anilines with high conversion rates. In this process, the PNP-SSS catalyst can be reused more than five times with almost consistent efficiency.

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Acknowledgements

The authors appreciate partial financial supports from Alzahra University. M.M.H. is also thankful to Iran National Science Foundation (INSF) for the individual given grant.

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Authors and Affiliations

  1. Department of Chemistry, School of Physics and Chemistry, Alzahra University, Tehran, Iran

    Leyla Mohammadkhani & Majid M. Heravi

  2. Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, Iran

    Farhad Panahi

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  1. Leyla Mohammadkhani
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  2. Majid M. Heravi
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  3. Farhad Panahi
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Correspondence to Majid M. Heravi or Farhad Panahi.

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Mohammadkhani, L., Heravi, M.M. & Panahi, F. Efficient and heterogeneous transfer hydrogenation of nitroarenes using immobilized palladium nanoparticles on silica–starch substrate (PNP-SSS). Monatsh Chem 153, 623–633 (2022). https://doi.org/10.1007/s00706-022-02932-w

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  • DOI: https://doi.org/10.1007/s00706-022-02932-w

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