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Hydrated clusters of organic molecules generated by IR OPO resonant desorption of frozen aqueous solutions

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Abstract

Long series of hydrated clusters of organic molecules (formaldehyde, methanol, ethanol and tryptophan) have been generated by infrared optical parametric oscillator (OPO) resonant desorption of frozen aqueous solutions. Using a comparative approach, we derived some general trends from cluster size and velocity distribution measurements. In the biologically interesting case of tryptophan amino acid, our technique yields a much longer (and complete) series of hydrated clusters than that obtained previously using a combined laser desorption/pulsed jet expansion technique [L.C. Snoek, R.T. Kroemer, J.P. Simons: Phys. Chem. Chem. Phys. 4, 2130 (2002)].

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Correspondence to C. Focsa.

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79.20.La; 36.40.-c; 82.80.Ms

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Ziskind, M., Mihesan, C., Lebrun, N. et al. Hydrated clusters of organic molecules generated by IR OPO resonant desorption of frozen aqueous solutions. Appl. Phys. A 79, 991–995 (2004). https://doi.org/10.1007/s00339-004-2612-3

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  • DOI: https://doi.org/10.1007/s00339-004-2612-3

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