Abstract
The exciton binding energy is one of the key parameters that govern the physics of many opto-electronic organic devices. It is shown that the previously reported values for the exciton binding energies in many organic semiconductors, which differ by more than an order of magnitude, can be consistently rationalized within the framework of the charging energy of the molecular units, with a simple dependence of the exciton binding energy on the length of these units. The implications of this result are discussed.
Similar content being viewed by others
References
C.W. Tang, S.A. van Slyke: Appl. Phys. Lett. 51, 913 (1987)
J.H. Burroughes, D.D.C. Bradley, A.R. Brown, R.N. Marks, K. McKay, R.H. Friend, P.L. Burn, A.B. Holmes: Nature 347, 539 (1990)
N.S. Sariciftci, L. Smilowitz, A.J. Heeger, F. Wudl: Science 258, 1474 (1992)
G. Weiser: Phys. Rev. B 45, 14076 (1992)
R.N. Marks, J.J.M. Halls, D.D.C. Bradley, R.H. Friend, A.B. Holmes: J. Phys.: Condens. Matter 6, 1379 (1994)
T.W. Hagler, K. Pakbaz, A.J. Heeger: Phys. Rev. B 49, 10968 (1994)
J.M. Leng, S. Jeglinski, R.E. Brenner, Z.V. Vardeny, F. Guo, S. Mazumdar: Phys. Rev. Lett. 72, 156 (1994)
R. Kersting, U. Lemmer, M. Deussen, H.J. Bakker, R.F. Marth, H. Kurz, V.I. Arkhipov, H. Bässler, E.O. Göbel: Phys. Rev. Lett. 73, 1440 (1994)
L.M. Blinov, S.P. Palto, G. Ruani, C. Taliani, A.A. Tevosov, S.G. Yudin, R. Zamboni: Chem. Phys. Lett. 232, 401 (1995)
Y. Yang, Q. Pei, A.J. Heeger: Synth. Met. 78, 263 (1996)
J.L. Brédas, J. Cornil, A.J. Heeger: Adv. Mater. 8, 44 (1996)
I.H. Campbell, T.W. Hagler, D.L. Smith, J.P. Ferraris: Phys. Rev. Lett. 76, 1900 (1996)
M. Liess, S. Jeglinski, Z.V. Vardeny, M. Ozaki, K. Yoshino, Y. Ding, T. Barton: Phys. Rev. B 56, 15712 (1997)
S.F. Alvarado, P.F. Seidler, D.G. Lidzey, D.D.C. Bradley: Phys. Rev. Lett. 81, 1082 (1998)
I.G. Hill, A. Kahn, Z.G. Soos, R.A. Pascal Jr.: Chem. Phys. Lett. 327, 181 (2000)
D. Moses, J. Wang, A.J. Heeger, N. Kirova, S. Brazowski: Synth. Met. 119, 503 (2001)
M. Knupfer, H. Peisert, T. Schwieger: Phys. Rev. B 65, 033204 (2002)
C.I. Wu, Y. Hirose, H. Sirringhaus, A. Kahn: Chem. Phys. Lett. 272, 43 (1997)
R.W. Lof, M.A. van Veenendaal, B. Koopmans, H.T. Jonkman, G.A. Sawatzky: Phys. Rev. Lett. 68, 3924 (1992)
P.A. Brühwiler, A.J. Maxwell, A. Nilsson, N. Martensson, O. Gunnarsson: Phys. Rev. B 48, 18296 (1993)
M. Knupfer, D.M. Poirier, J.H. Weaver: Phys. Rev. B 49, 2281 (1994)
B. Schweitzer, H. Bässler: Synth. Met. 109, 1 (2000)
R.C. Haddon, T. Siegrist, R.M. Fleming, P.M. Bridenbaugh, R.A. Laudise: J. Mater. Chem. 5, 1719 (1995)
T. Siegrist, Ch. Kloc, R.A. Laudise, H.E. Katz, R.C. Haddon: Adv. Mater. 10, 379 (1998)
P. Puschnig, C. Ambrosch-Draxl: Phys. Rev. B 60, 7891 (1999)
H. Schürmann, N. Koch, A. Vollmer, S. Schrader, N. Neumann: Synth. Met. 111–112, 591 (2000)
P. Puschnig, C. Ambrosch-Draxl: Synth. Met. 119, 245 (2001)
J. Cornil, D. Beljonne, J.-P. Calbert, J.-L. Brédas: Adv. Mater. 13, 1053 (2001) and references therein
J. Cornil, D. Beljonne, J.-L. Brédas: J. Chem. Phys. 103, 842 (1995)
E. Zojer, M. Knupfer, Z. Shuhai, J. Fink, J.-L. Brédas, H.-H. Hörhold, J. Grimme, U. Scherf, T. Benincori, G. Leising: Phys. Rev. B 61, 16561 (2000)
E. Zojer, J. Cornil, G. Leising, J.-L. Brédas: Phys. Rev. B 59, 7957 (1999)
J.-W. van der Horst, P.A. Bobbert, M.A.J. Michels, H. Bässler: J. Chem. Phys. 114, 6950 (2001)
M. Pope, C.E. Swenberg: Electronic Processes in Organic Crystals and Polymers (Oxford University Press, Oxford 1999) and references therein
S.J. Tans, M.H. Devoret, H. Dai, A. Thess, R.E. Smalley, L.J. Geerligs, C. Dekker: Nature 386, 474 (1997)
T. Pichler, M. Knupfer, M.S. Golden, J. Fink, A. Rinzler, R.E. Smalley: Phys. Rev. Lett. 80, 4729 (1998)
A. Ruini, M.J. Caldas, G. Bussi, E. Molinari: Phys. Rev. Lett. 88, 206403 (2002)
M. Knupfer, T. Schwieger, J. Fink, K. Leo, M. Hoffmann: Phys. Rev. B 66, 035208 (2002)
M. Hoffmann, K. Schmidt, T. Fritz, T. Hasche, V.M. Agranovich, K. Leo: Chem. Phys. 258, 73 (2000)
D.A. dos Santos, D. Beljonne, J. Cornil, J.L. Brédas: Chem. Phys. 227, 1 (1998)
M. Rohlfing, S.G. Louie: Phys. Rev. Lett. 82, 1959 (1999)
M. Knupfer, T. Pichler, M.S. Golden, J. Fink, M. Murgia, R.H. Michel, R. Zamboni, C. Taliani: Phys. Rev. Lett. 83, 1443 (1999)
M. Knupfer, J. Fink, E. Zojer, G. Leising, D. Fichou: Chem. Phys. Lett. 318, 585 (2000)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
71.35.-y; 78.20.-e; 78.66.Qn
Rights and permissions
About this article
Cite this article
Knupfer, M. Exciton binding energies in organic semiconductors. Appl. Phys. A 77, 623–626 (2003). https://doi.org/10.1007/s00339-003-2182-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-003-2182-9