Skip to main content

Advertisement

Log in

Trace element distribution and geochemical zonation in the world-class Nowa Sól sediment-hosted Cu-Ag deposit, SW Poland

  • Article
  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

More than 200 samples from sediment-hosted Lower Zechstein Cu-Ag series of the newly discovered Nowa Sól deposit (SW Poland) were studied in order to determine spatial and vertical correlations between the metals. On the basis of obtained metal distribution, the investigated deposit can be subdivided into two parts. Rare earth elements and gold concentrations are elevated in the southwestern part of the deposit, close to the Rote Fäule area. Silver cobalt, rhenium, lead, and zinc are concentrated in a wide polymetallic zone in the northeastern part of the deposit. The concentration patterns of most metals are controlled by the distance from the Zielona Góra oxidized field. Copper content does not vary significantly across the deposit. The contents of molybdenum, nickel, and vanadium seem to depend on the lithotype rather than on broader metal distribution. In general, the highest ore grades are observed in the organic-rich variety of the Kupferschiefer, in the uppermost mineralized Weissliegend, and in the base of the Zechstein limestone. Metal zonation of the Nowa Sól deposit can be drawn in the following order from southwest to northeast: (1) Au-rare earth element (REE)-bearing transitional zone, (2) REE-enriched Cu-bearing reduced zone, (3) Ag-Re-Co-enriched Cu-bearing reduced zone, (4) Pb-Ag-Co-enriched Cu-bearing reduced zone, and (5) Pb-bearing reduced zone. Distribution of metals across the investigated area supports an epigenetic model involving multistage and fault-controlled ore-forming processes. It is plausible that the volume, temperature, chemical composition, and time of activity of the metalliferous fluids have differed across the northern part of the Fore-Sudetic Monocline. The polymetallic Nowa Sól deposit, hosting estimated, inferred, and indicated resources of 10.6 Mt of Cu and 36.4 kt of Ag, is part of a broader mineralized trend. The deposit is open towards the west and northwest; the prognostic area with hypothetical resources, covering more than 500 km2 has been delineated in the northwestern part of the Fore-Sudetic Monocline, where at least 50 Mt of Cu and 120 kt of Ag can still be discovered and documented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Data availability

The authors declare that data presented in the article was obtained by the Miedzi Copper Corporation during its exploration program in Poland. Miedzi Copper is an owner of all raw results of the chemical assays.

Code availability

Not applicable.

References

  • Alderton DHM, Selby D, Kucha H, Blundell DJ (2016) A multistage origin of the Kupferschiefer mineralization. Ore Geol Rev 79:535–543

    Article  Google Scholar 

  • Auguścik J, Mucha J, Wasilewska-Błaszczyk M (2016) Study of variability structure of accumulation index of accompanying elements (As Co, Pb) in the Cu-Ag deposits (LGOM, Rudna Mine): useful or needless? Górnictwo Odkrywkowe 57:36–43

    Google Scholar 

  • Banaś M Kijewski P and Salamon W 2007 Pierwiastki towarzyszące szkodliwe dla procesu produkcji i środowiska naturalnego. In: Piestrzyński A., eds. Monografia KGHM Polska Miedź S.A. 278 282 (In Polish)

  • Barbalance K, Periodic table of elements. Available online: https://environmentalchemistry.com/yogi/periodic (accessed on 10 May 2020)

  • Becker F, Bechstädt T (2006) Sequence stratigraphy of a carbonate-evaporate succession (Zechstein 1, Hessian Basin, Germany). Sedimentology 53:1083–1120

    Article  Google Scholar 

  • Bechtel A, Ghazi AM, Elliott WC, Oszczepalski S (2001) The occurrences of the rare earth elements and the platinum group elements in relation to base metal zoning in the vicinity of Rote Fäule in the Kupferschiefer, Poland. Appl Geochem 16:375–386

    Article  Google Scholar 

  • Bechtel A, Gratzer R, Puttmann W, Oszczepalski S (2001) Variable alteration of organic matter in relation to metal zoning at the Rote Fäule front (Lubin-Sieroszowice mining district, SW Poland). Org Geochem 32(3):377–395

    Article  Google Scholar 

  • Bechtel A, Sun Y, Püttmann W, Hoernes S, Hoefs J (2001) Isotopic evidence for multi-stage metal enrichment in the Kupferschiefer from the Sangerhausen Basin, Germany. Chem Geol 176:31–49

    Article  Google Scholar 

  • Bechtel A, Gratzer R, Püttmann W, Oszczepalski S (2002) Geochemical characteristics across the oxic/anoxic interface (Rote Fäule front) within the Kupferschiefer of the Lubin-Sieroszowice mining district (SW Poland). Chem Geol 185:9–31

    Article  Google Scholar 

  • Bechtel A, Püttmann W (1992) Combined isotopic and biomarker investigations of temperature- and facies-dependent variations in the Kupferschiefer of the Lower Rhine Basin, northwestern Germany. Chem Geol 102:23–40

    Article  Google Scholar 

  • Bechtel A, Püttmann W (1997) Paleooceanography of the early Zechstein Sea during Kupferschiefer deposition in the Lower Rhine Basin (Germany): a reappraisal from stable isotope and organic geochemical investigations. Palaeogeogr Palaeoclimatol Palaeoecol 136:331–358

    Article  Google Scholar 

  • Bieńko T 2019 Relations between matrix type and style of mineralization in sandstone ore, Nowa Sól Cu-Ag deposit, SW Poland. Life with Ore Deposits – Proceedings of the 15th SGA Biennal Meeting, Glasgow, Scotland, 27–30 August 2019: 25–28

  • Blengini GA, Latunussa CEL, Eynard U, Torres de Matos C, Wittmer D, Georgitzikis K, Pavel C, Carrara S, Mancini L, Unguru M, Blagoeva D, Mathieux F and Pennington D (2020) Study on the EU’s list of critical raw materials, European Commission.

  • Blundell DJ, Karnkowski PH, Alderton DHM, Oszczepalski S, Kucha H (2003) Copper mineralization of the Polish Kupferschiefer – a proposed basement fault-fracture system of fluid flow. Econ Geol 98:1487–1495

    Article  Google Scholar 

  • Błaszczyk JK (1981) Wpływ paleomorfologii stropu białego spągowca na zmienność facjalną serii złożowej w zagłębiu lubińskim. Geol Sudet 16:195–215 (In Polish)

    Google Scholar 

  • Borg G (1991) The significance of Rotliegend volcanics for the metal province of the Kupferschiefer Basin. Zenterblatt Für Geologie Und Paläontologie 4(1):929–943

    Google Scholar 

  • Borg G, Piestrzyński A, Bachmann G, Püttmann W, Walther S, Fiedler M (2012) An overview of the European Kupferschiefer deposits In: Hedenquist JW Harris M and Camus F (ed.) Geology and genesis of major copper deposits and districts of the world: a tribute to Richard H Sillitoe. Spec Publ Soc Econ Geol 16:455–486

    Google Scholar 

  • Brauns CM, Pätzold T, Haack U (2003) A Re-Os study bearing on the age of the Kupferschiefer mineralization at Sangerhausen (Germany): XV International Congress of Carboniferous and Permian Stratigraphy. Abstracts, Utrecht, p 66

    Google Scholar 

  • Cook NJ, Ciobanu CL, Pring A, Skinner W, Shimizu M, Danyushevsky L, Saini-Eidukat B, Melcher F (2009) Trace and minor elements in sphalerite A LA-ICPMS study. Geochmicia et Cosmochimica Acta 73:4761–4791

  • Dryssen D, Kremling K (1990) Increasing hydrogen sulfide concentration and trace metal behavior in the anoxic Baltic waters. Mar Geochem 30:193–204

    Google Scholar 

  • Gast R, Dusar M, Breitkreutz C, Gaupp R, Scheider JW, Stemmerik GM, Geissler M, Kiersnowski H, Glennie K, Kabel S, Johnes N (2010) Chapter 7 – Rotliegend. In: Doornenbal H, Stevenson A (eds) Petroleum geological atlas of the Southern Permian Basin area. Netherlands, EAGE Publications, Houten, pp 101–121

    Google Scholar 

  • Glennie KW, Buller AT (1983) The Permian Weissliegend of NW Europe: the partial deformation of aeolian dune sands caused by the Zechstein Transgression. Sed Geol 35:43–81

    Article  Google Scholar 

  • Hitzman M Kirkham R Broughton D Thorson J and Selly D 2005 The sediment-hosted stratiform copper ore system. In: Hedenquist JW, Goldfarb RJ and Richards JP, eds. Economic Geology – one hundredth anniversary volume 1905 – 2005. Soc Econ Geol 609 642

  • Jerzykiewicz M, Kijewski P, Mroczkowski J, Teisseyre AK (1976) Geneza osadów białego spągowca monokliny przedsudeckiej. Geol Sudet 11:57–89 (In Polish)

    Google Scholar 

  • Kaczmarek W, Wasilewska-Błaszczyk M, Dudek M (2018) The impact of variability of reservoir rocks on the quality of parameters of the Cu-Ag deposit, Lubin-Głogów Copper District (LGCD). Biuletyn Państwowego Instytutu Geologicznego 472:105–119 (In Polish with English summary)

    Article  Google Scholar 

  • Karnkowski P (1994) Rotliegend lithostratigraphy in the central part of the Polish Permian Basin. Geological Quarterly 38:27–42

    Google Scholar 

  • Kiersnowski H, Buniak A (2006) Evolution of the Rotliegend Basin of northwestern Poland. Geol Q 50:119–138

    Google Scholar 

  • Kiersnowski H, Peryt TM, Buniak A, Mikołajewski Z (2009) From the intra-desert ridges to the marine carbonate island chain: paleogeography, depositional history and tectonic evolution of the Permian, Upper Rotliegend-Lower Zechstein Wolsztyn-Pogorzela Ridge, West Poland. Geol J 45:319–335

    Article  Google Scholar 

  • Kozub-Budzyń G, Piestrzyński A (2017) Geochemical characteristic of Ag-bearing minerals occurring in copper ore deposit at the Fore-Sudetic Monocline. Biuletyn Państwowego Instytutu Geologicznego 468:49–60

    Article  Google Scholar 

  • Kucha H (1986) Two-brine model of the genesis of strata-bound Zechstein deposits (Kupferschiefer type), Poland. Miner Deposita 21:70–80

    Article  Google Scholar 

  • Kucha H (1990) Geochemistry of the Kupferschiefer, Poland. Geol Rundsch 79:387–399

    Article  Google Scholar 

  • Kucha H 2003 Geology, mineralogy and geochemistry of the Kupferschiefer Poland. In: Kelly J. et al., eds. Europe’s Major Base Metal Deposits. Irish Association for Economic Geol 215–238

  • Legler B, Gebhardt U, Schneider JW (2005) Late Permian nonmarine-marine transitional profiles in the central Southern Permian Basin, Northern Germany. Int J Earth Sci 94:851–862

    Article  Google Scholar 

  • Legler B, Schneider JW (2008) Marine ingressions into the Middle/Late Permian saline lake of the Southern Permian Basin (Rotliegend, Northern Germany) possibly linked to sea-level highlands in the Arctic rift system. Paleogeogr Paleoclimatol Paleoecol 267:102–114

    Article  Google Scholar 

  • Lewan MD (1984) Factors controlling the proportionality of vanadium and nickel in crude oils. Geochim Cosmochim Acta 48:2231–2238

    Article  Google Scholar 

  • McDonough WF, Sun SS (1995) The composition of the Earth. Chem Geol 120:223–253

    Article  Google Scholar 

  • McLennan SM (1989) Rare earth elements in sedimentary rocks: Influence of provenance and sedimentary processes. Rev Mineral Geochem 21:169–200

    Google Scholar 

  • Mei S, Henderson C (2001) Evolution of Permian conodont provincialism and its significance in global correlation and paleoclimate implication. Paleogeogr Paleoclimatol Paleoecol 170:237–260

    Article  Google Scholar 

  • Mikulski S, Oszczepalski S, Sadłowska K, Chmielewski A, Małek R (2020) Trace element distributions in the Zn-Pb (Mississippi Valley-Type) and Cu-Ag (Kupferschiefer) sediment-hosted deposits in Poland. Minerals 10(75):1–47

    Google Scholar 

  • Mikulski S, Stein H (2017) Re-Os isotopic age of the Cu-Ag sulphide ore and its mineralogical and geochemical characteristic from the Lubin-Polkowice mining area (SW Poland). Biuletyn Państwowego Instytutu Geologicznego 468:79–96 (In Polish with English summary)

    Article  Google Scholar 

  • Mucha J, Nieć M, Szwed E (2005) Estimation accuracy of accompanying elements in Cu-Ag deposits of LGOM (Legnica-Głogów Copper Region). Przegląd Geologiczny 61(11):49–56 (In Polish with English summary)

    Google Scholar 

  • Mucha J, Wasilewska-Błaszczyk M (2012) Variability anisotropy of mineral deposits parameters and its impact on resources estimation – a geostatistical approach. Mineral Res Manag 28:113–135

    Google Scholar 

  • Namysłowska-Wilczyńska B (1986) Analysis of variance in investigations on anisotropy of Cu ore deposits. Miner Deposita 21:253–262

    Article  Google Scholar 

  • Nemec W, Porębski SJ (1977) Weissliegendes sandstones: a transition from fluvial-aeolin to shallow-marine sedimentation (Permian of Fore-Sudetic Monocline). Ann Soc Geol Pol 47:387–418

    Google Scholar 

  • Nieć M (1964) Analiza statystyczna złóż miedzi monokliny przedsudeckiej. Rudy Metali Nieżelaznych 9(6):300–302 (In Polish)

    Google Scholar 

  • Oszczepalski S 1989 Kupferschiefer in southwestern Poland – sedimentary environments, metal zoning, and ore controls In Boyle RW Brown AC Jefferson CW Jowett EC and Kirkham RV (ed.) Sediment hosted stratiform copper deposits. Geol Assoc Can Spec Pap 36 571-600

  • Oszczepalski S (1999) Origin of the Kupferschiefer polymetallic mineralization in Poland. Miner Deposita 34:599–613

    Article  Google Scholar 

  • Oszczepalski S and Chmielewski A 2015 Litologia i okruszcowanie utworów kontaktu cechsztynu z czerwonym spągowcem. In: Leszczyński K., eds. Profile Głębokich otworów wiertniczych – Sława IG-1, Zeszyt 146. Polish Geological Institute – National Research Institute, Warsaw, Poland. 142 (In Polish with English summary).

  • Oszczepalski S, Chmielewski A, Mikulski S (2016) Controls of the distribution of rare earth elements in the Kupferschiefer series of SW Poland. Geolog Q 60:811–826

    Google Scholar 

  • Oszczepalski S Chmielewski A and Rydzewski A 2019a Mineralizacja kruszcowa w utworach cechsztyńskiej serii miedzionośnej. In: Oszczepalski S and Chmielewski A, eds. Profile Głębokich otworów wiertniczych – Grochowice M 9, Zeszyt 153. Polish Geological Institute – National Research Institute, Warsaw, Poland. 149 (In Polish with English summary)

  • Oszczepalski S, and Rydzewski A (1987) Paleogeography and sedimentary model of the Kupferschiefer in Poland. Lecture Notes on the Earth Sciences 10, The Zechstein facies in Europe. pp. 189–205.

  • Oszczepalski S and Rydzewski A 1997 Metallogenic atlas of the Zechstein copper-bearing series in Poland; Polish Geol Inst, 32 16 oversize plates

  • Oszczepalski S, Speczik S, Zieliński K, Chmielewski A (2019) The Kupferschiefer deposits and prospects in SW Poland: Past. Present and Future Minerals 9(10):592–633

    Google Scholar 

  • Pašava J, Oszczepalski S, Du A (2010) Re-Os age of non-mineralized black shale from the Kupferschiefer, Poland, and implications for metal enrichment. Miner Deposita 45:189–199

    Article  Google Scholar 

  • Pašava J, Vymazalová A, Mao J, Du A, Qu W, Korzekwa, W (2007) Re-Os study of noble metal-rich black shales from the Polish Kupferschiefer. In: Andrew CJ (ed) Digging Deeper, Irish Association for Economic Geology, Dublin, Ireland, pp 221–224

  • Pätzold T Brauns CM Haack U 2002 A Re-Os study bearing on the age of the Kupferschiefer mineralization at Mansfeld (Germany). Highly siderophile elements in terrestrial and meteoritic samples: implications for planetary differentiation and igneous processes. Nancy, France. 26–28 August 2002 [workshop].

  • Peryt TM, Geluk MC, Mathiesen APJ, Smith K (2010) Chapter 8 – Zechstein. In: Doornenbal H, Stevenson A (eds) Petroleum geological atlas of the Southern Permian Basin area. Netherlands, EAGE Publications, Houten, pp 123–148

    Google Scholar 

  • Peryt TM, Durakiewicz T, Kotarba MJ, Oszczepalski S, Peryt D (2012) Carbone isotope stratigraphy of the basal Zechstein (Lopingian) strata in Northern Poland and its global correlation. Geol Q 56:285–298

    Google Scholar 

  • Pieczonka J (2011) Factors controlling distribution of ore minerals within copper deposit, Fore-Sudetic Monocline, SW Poland. Wydawnictwo AGH, Kraków, Poland. (In Polish with English summary)

  • Pieczonka J and Piestrzyński A 2015 Mineral zonation in the Kupferschiefer-type deposit, Lubin-Sieroszowice mining district, SW Poland. Mineral Resources in Sustainable World – Proceedings of the 13th SGA Biennal Meeting, Nancy, France, 24–27 August 2015 1985–1988

  • Pieczonka J, Piestrzyński A, Lenik P, Czerw H (2007) Distribution of ore minerals in the copper deposit, Fore-Sudetic Monocline. SW Poland Biul Państwowego Instytutu Geologicznego 423:95–108 (in Polish with English abstract)

    Google Scholar 

  • Pieczonka J, Piestrzyński A, Mucha J, Głuszek A, Kotarba M, Więcław D (2009) The red-bed-type precious metal deposit in the Sieroszowice-Polkowice copper mining district, SW Poland. Ann Soc Geol Pol 78:151–280

    Google Scholar 

  • Piestrzyński A, Pieczonka J, Głuszek A (2002) Redbed-type gold mineralisation, Kupferschiefer, south-west Poland. Miner Deposita 37:512–528

    Article  Google Scholar 

  • Piestrzyński A, Wodzicki A (2000) Origin of the gold deposit in the Polkowice-West Mine, Lubin-Sieroszowice Mining District, Poland. Miner Deposita 35:37–47

    Article  Google Scholar 

  • Püttmann W, Hagemann HW Merz C and Speczik S 1988 Influence of organic material on mineralization processes in the Permian Kupferchiefer formation, Poland. Organic Geochem 357–363

  • Püttmann W, Merz C, Speczik S (1989) The secondary oxidation of organic material and its influence on Kupferschiefer mineralization of southwest Poland. Appl Geochem 4:141–151

    Article  Google Scholar 

  • Radliński M, Sawłowicz Z (2017) Altered rhythmic sulphide bands in the Weissliegend sandstone in the Rudna mine (Fore-Sudetic Monocline, Poland). Biuletyn Państwowego Instytutu Geologicznego 468:61–78 (In Polish with English summary)

    Article  Google Scholar 

  • Rentzsch J, Franzke HJ (1997) Regional tectonic control of the Kupferschiefer mineralization in the Central Europe. Zeitschrift Für Geologische Wissenchaften 25:141–149

    Google Scholar 

  • Rentzsch J, Knitzschke G (1968) Erzmineralparagenesen des Kupferschiefer und ihre regionale Verbreitung. Freiberger Forschungsheft 231:189–211

    Google Scholar 

  • Rimmer SM (2004) Geochemical paleoredox indicators in Devonian – Mississippian black shales, Central Appalachian Basin (USA). Chem Geol 206:373–391

    Article  Google Scholar 

  • Ripley EM, Shaffer NR, Gilstrap MS (1990) Distribution and geochemical characteristics of metal enrichment in the New Albany shale (Devonian – Mississippian), Indiana. Econ Geol 85:1790–1807

    Article  Google Scholar 

  • Romanowska B, Salski W (1977) Zmienność złoża rud miedzi monokliny przedsudeckiej. Geol Sudet 12(2):49–77 (in Polish with English summary)

    Google Scholar 

  • Ruebsam W, Dickson AJ, Hoyer EM, Schwark L (2017) Multiproxy reconstruction of oceanographic conditions in the southern epeiric Kupferschiefer Sea (Late Permian) based on redox-sensitive trace elements, molybdenum isotopes and biomarkers. Gondwana Res 44:205–218

    Article  Google Scholar 

  • Rydzewski A (1978) Oxidated facies of the copper-bearing Zechstein shale in the Fore-Sudetic monocline. Przegląd Geologiczny 26:102–108 (in Polish with English summary)

    Google Scholar 

  • Sawłowicz Z (1990) Primary copper sulfides from the Kupferschiefer, Poland. Miner Deposita 25:262–271

    Article  Google Scholar 

  • Sawłowicz Z (2013) REE and their relevance to the development of the Kupferschiefer copper deposit in Poland. Ore Geol Rev 55:176–186

    Article  Google Scholar 

  • Sawłowicz Z, Wadepohl KH (1992) The origin of rhythmic sulphide bands from the Permian sandstones (Weissliegendes) in the footwall of the Fore-Sudetic Kupferschiefer. Miner Deposita 27:242–248

    Article  Google Scholar 

  • Speczik S (1994) Kupferschiefer mineralization in the light of organic geochemistry and coal petrology studies. Geological Quarterly 38(4):639–650

    Google Scholar 

  • Speczik S (1995) The Kupferschiefer mineralization of Central Europe: new aspects and major areas of future research. Ore Geol Rev 9:411–426

    Article  Google Scholar 

  • Speczik S (2019) Geological documentation of the Nowa Sól Cu-Ag ore deposit, SW Poland. Zielona Góra Copper, Warsaw (in Polish, unpublished).

  • Speczik S (2020) Geological documentation of the Mozów Cu-Ag ore deposit, SW Poland. Mozów Copper, Warsaw (in Polish, unpublished).

  • Speczik Ñ, Dziewińska L, Pepel A, Jóźwiak W (2012) Reprocessing of archival geophysical data as useful instrument in Cu-Ag deposit prospection of Fore-Sudetic Monocline. Biuletyn Państwowego Instytutu Geologicznego 452:257–286 (in Polish with English abstract)

    Google Scholar 

  • Speczik S Dziewińska L Jóźwiak W and Zieliński K 2020 Application of historical geophysical materials in searching for Cu-Ag ore deposits – a new direction of research. Minerals 10 8 725 1–24.

  • Speczik S, Skowronek C, Friedrich G, Diedel R, Schumacher C, Schmidt FP (1986) The environment of generation of some base metal Zechstein occurrences in Central Europe. Acta Geol Pol 36:1–35

    Google Scholar 

  • Speczik S, Zieliński K, Bieńko T, Pietrzela A (2021) The prospecting strategy for a deep Cu-Ag ore deposits in Poland – an anatomy of success. Ore Geol Rev 131:1–12

    Article  Google Scholar 

  • Sun YZ, Püttmann W (1997) Metal accumulation during and after deposition of the Kupferschiefer from the Sangerhausen Basin, Germany. Appl Geochem 12:577–592

    Article  Google Scholar 

  • Sun YZ, Püttmann W, Speczik S (1995) Differences in the depositional environment of basal Zechstein in southwest Poland – implications for base metal mineralization. Org Geochem 23:819–835

    Article  Google Scholar 

  • Swanner ED, Planavsky NJ, Lalonde SV, Robbins LJ, Bekker A, Rouxel OJ, Saito MA, Kappler A, Mojzsis SJ, Konhauser KO (2014) Cobalt and marine redox evolution. Earth Planet Sci Lett 390:253–263

    Article  Google Scholar 

  • Symons DTA, Kawasaki K, Walther S, Borg G (2011) Paleomagnetism of the Cu-Zn-Pb-bearing Kupferschiefer black shale (Upper Permian) at Sangerhausen, Germany. Miner Deposita 46:137–152

    Article  Google Scholar 

  • Szuflicki M, Malon A and Tymiński M (2020) Bilans zasobów złóż kopalin w Polsce wg stanu na 31 XII 2019 r.: Polish Geological Institute – National Research Institute, Warsaw, Poland. 262 p. (In Polish).

  • Talor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, Malden, MA

    Google Scholar 

  • Tylka M, Mayer W, Piestrzyński A, Tylka W (1980) Zmienność okruszcowania miedziowego w wybranych rejonach kopalni Rudna. Kwartalnik Geologiczny 25(2):261–274 (in Polish with English summary)

    Google Scholar 

  • Vaughan DJ, Sweeney MA, Friedrich G, Diedel R, Harańczyk C (1989) The Kupferschiefer – an overview with an appraisal of the different types of mineralization. Econ Geol 84:1003–1027

    Article  Google Scholar 

  • Vine JD, Tourtelot EB (1970) Geochemistry of black shale deposits – a summary report. Econ Geol 65:253–272

    Article  Google Scholar 

  • Wadepohl KH (1971) Environmental influences of the chemical composition of shales and clays In: Ahrens LH Press F Runcorn SK Urey HC (ed.). Phys Chem Earth 8:307–331

    Article  Google Scholar 

  • Wagner R 1994 Stratigraphy and development of the Zechstein Basin in Poland. Prace Państwowego Instytutut Geologicznego 146: 1–71 (In Polish, with English abstract)

  • Wagner R, Peryt TM (1997) Possibility of sequence stratigraphic subdivision of the Zechstein in the Polish Basin. Geol Q 41:457–474

    Google Scholar 

  • Wagner T, Lorenz J (2002) Mineralogy of complex Co-Ni-Bi vein mineralization, Bieber deposit, Spessart, Germany. Mineral Mag 66:385–407

    Article  Google Scholar 

  • Wagner T, Okrusch M, Weyer S, Lorentz J, Lahaye Y, Taubald H, Schmitt RT (2010) The role of the Kupferschiefer in the formation of hydrothermal base metal mineralization in the Spessart ore district, Germany: insight from detailed sulfur isotope studies. Miner Deposita 45:217–239

    Article  Google Scholar 

  • Wodzicki A, Piestrzyński A (1994) An ore genetic model for the Lubin-Sieroszowice mining district, Poland. Miner Deposita 29:30–43

  • Ziegler PA 1990 Geological atlas of Western and Central Europe (2nd ed.). Shell Internationale Petroleum Maatschappij. 238 p 52 enclosures

  • Zientek ML Oszczepalski S Parks HL Bliss JD Borg G Box SE Denning PD Hayes TS Spieth V and Taylor CD 2015 Assessment of undiscovered copper resources associated with the Permian Kupferschiefer, Southern Permian Basin, Europe. In: Zientek ML, Hammarstrom JM and Johnson KM (ed.) Global mineral resource assessment. Reston, Virginia, U.S. Geological Survey. 94 p

Download references

Acknowledgements

The authors would like to acknowledge Stanisław Speczik for the writing assistance, a critical revision of the manuscript, and for sharing the research material. We are indebted to Krzysztof Zieliński from the MCC for a language revision. We would also like to thank the reviewers Adam Piestrzyński and Gregor Borg for the constructive comments to the manuscript. We acknowledge Bernd Lehman and Hartwig Frimmel for the editorial handling and supporting us in getting this paper into a publishable form. Finally, we would like to pay our special regards to Leo Hatheway and Lyle Braaten from Miedzi Copper Corporation, who allowed us to study core samples from the Nowa Sól deposit.

Author information

Authors and Affiliations

Authors

Contributions

TB contributed to the conception and design of the manuscript, collected the data, calculated the raw results, performed the statistical computing, prepared the maps and figures, contributed to the data interpretation, and wrote the paper; AP collected the data, contributed to the data interpretation, and participated in the revisions of paper.

Corresponding author

Correspondence to Tomasz Bieńko.

Ethics declarations

Conflict of interest

The authors declare no competing interests.

Additional information

Editorial handling: H. Frimmel

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (JPG 955 KB)

Supplementary file2 (DOCX 18 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bieńko, T., Pietrzela, A. Trace element distribution and geochemical zonation in the world-class Nowa Sól sediment-hosted Cu-Ag deposit, SW Poland. Miner Deposita 57, 827–851 (2022). https://doi.org/10.1007/s00126-022-01110-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00126-022-01110-6

Keywords

Navigation