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Interactions between macromolecules in solution and intermacromolecular complexes

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Book cover Interactions Between Macromolecules in Solution and Intermacromolecular Complexes

Part of the book series: Advances in Polymer Science ((POLYMER,volume 45))

Abstract

Macromolecules with complementary binding sites associate almost stoichiometrically in solution to form the “intermacromolecular complex”. Studies on intermacromolecular complexes are mainly concerned with the elucidation of various reactions in vivo essential for the maintenance of life. They also provide indispensable information on the production of new macromolecular materials.

In this review, the results of fundamental studies on the characteristics of intermacromolecular complexes considering their formation, structure and physical and chemical properties are systematically discussed. These complexes are divided into four classes on the basis of their main interaction forces, i.e. polyelectrolyte complexes, hydrogen-bonding complexes, stereocomplexes and charge-transfer complexes. The cooperative phenomena of the formation of intermacromolecular complexes are also discussed quantitatively. Moreover, up-to-date topics from various fields and their various possibilities of application for future developments are mentioned.

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  1. Koji Abe

    Present address: Department Functional Polymer Science, Shinshu University, 386, Ueda, Japan

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    Eishun Tsuchida & Koji Abe

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Tsuchida, E., Abe, K. (1982). Interactions between macromolecules in solution and intermacromolecular complexes. In: Tsuchida, E., Abe, K. (eds) Interactions Between Macromolecules in Solution and Intermacromolecular Complexes. Advances in Polymer Science, vol 45. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0017549

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