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Mössbauer study of iron/III/ pyropheophytins

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Abstract

/Pyropheophytinato a/ iron/III/ chloride [Fe/Pyropheo-a/Cl] and /pyropheophytinato b/ iron/III/ chloride [Fe/Pyropheo-b/Cl] have been prepared and characterized by Mössbauer spectroscopy. The Mössbauer parameters of the iron/III/pyropheophytins are similar to those of iron/III/ porphyrins. A comparison of the quadrupole splittings for the iron/III/ pyropheophytins with those for the iron/III/ pheophytins suggests that the deviations of the cyclopentenone ring and the saturated pyrrole ring from the macrocyclic plane become smaller with the removal of the methoxycarbonyl group.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Yokohama, 223, Japan

    H. Hori, K. Kadono, K. Fukuda, H. Inoue & T. Shirai

  2. Gmelin-Institut der Max-Planck-Gesellschaft, Varrentrappstrasse 40/42, D-6000, Frankfurt am Main 90, FRG

    E. Fluck

Authors
  1. H. Hori
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  2. K. Kadono
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  3. K. Fukuda
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  4. H. Inoue
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  5. T. Shirai
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  6. E. Fluck
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Hori, H., Kadono, K., Fukuda, K. et al. Mössbauer study of iron/III/ pyropheophytins. Journal of Radioanalytical and Nuclear Chemistry Letters 137, 277–286 (1989). https://doi.org/10.1007/BF02163553

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  • DOI: https://doi.org/10.1007/BF02163553

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