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Spectral-luminescent properties of actinides in elpasolite structure

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Abstract

Absorption, luminescence and self-luminescence spectra of transuranium elements (Np3+, Am3+, Cm3+) doped into Cs2NaLnCl6 (Ln=La, Lu) crystals are presented. In the case of Am3+ an attempt has been made to investigate luminescence excitation mechanisms. One of the luminescence features characteristic of the Am- and Cm-doped elpasolites appears to be dominante green glow. The octahedral ligand-field calculations were performed by the pair interaction method. The main properties of f-f transition spectra in crystals of elpasolite type are discussed.

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Authors and Affiliations

  1. V. G. Khlopin Radium Institute, Leningrad, (USSR)

    Yu. A. Barbanel', G. P. Chudnovskaya, Yu. I. Gavrish, R. B. Dushin, V. V. Kolin & V. P. Kotlin

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  1. Yu. A. Barbanel'
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  2. G. P. Chudnovskaya
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  3. Yu. I. Gavrish
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  4. R. B. Dushin
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  5. V. V. Kolin
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  6. V. P. Kotlin
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Barbanel', Y.A., Chudnovskaya, G.P., Gavrish, Y.I. et al. Spectral-luminescent properties of actinides in elpasolite structure. Journal of Radioanalytical and Nuclear Chemistry, Articles 143, 113–123 (1990). https://doi.org/10.1007/BF02117553

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  • DOI: https://doi.org/10.1007/BF02117553

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