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Stability and distribution constants of thallium(I) dialkyldithiophosphates

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Abstract

Stability and distribution constants of thallium(I) chelates with dimethyl-, diethyl-, di-(n-propyl)-, di-(n-propyl)-, di-(i-propyl)-, di-(n-butyl)-, di-(i-butyl)-, di-(sec-butyl)- and di-(i-amyl)-dithiophosphoric acids have been radiometrically determined using ion-exchange and extraction methods. The length of the alkyl chain influences considerably the distribution constant, however, it has only a small effect on the stability constant.

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Authors and Affiliations

  1. Department of Nuclear Chemistry, Czech Technical University, Břehová 7, Praha 1, Czechoslovakia

    J. Starý & K. Kratzer

  2. Department of Organic and Nuclear Chemistry, Charles University, Albertov 2030, Praha 2, Czechoslovakia

    L. Lešetický, V. Sváta & T. Vrbská

Authors
  1. J. Starý
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  2. K. Kratzer
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  3. L. Lešetický
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  4. V. Sváta
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  5. T. Vrbská
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Starý, J., Kratzer, K., Lešetický, L. et al. Stability and distribution constants of thallium(I) dialkyldithiophosphates. Journal of Radioanalytical and Nuclear Chemistry, Articles 157, 295–300 (1992). https://doi.org/10.1007/BF02047444

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  • DOI: https://doi.org/10.1007/BF02047444

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