Conclusions
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1.
Halogen-containing aza diene derivatives of polyfluoro aromatic compounds were obtained by reactions of pentafluoroaniline with haloolefins containing a CCl3 group at the C-C bond in the presence of AlCl3.
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2.
A mixture of cis and trans aza dienes is formed by pentafluoroaniline with cis-1-(pentafluorophenyl)-2-fluorotetrachloropropylene in the presence of AlCl3.
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3.
1,6-Dichloro-4-(pentafluorophenyl)-2,3-diaza-1,3-butadiene is formed by pentafluorobenzaldehyde hydrazone with CCl4 in the presence of AlCl3.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1651–1654, July, 1988.
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Kolesnikova, I.V., Ryabichev, A.G., Petrova, T.D. et al. Synthesis of halogen-containing aza and diaza diene derivatives of polyfluoro aromatic compounds. Russ Chem Bull 37, 1466–1469 (1988). https://doi.org/10.1007/BF00962764
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DOI: https://doi.org/10.1007/BF00962764