Abstract
The reactions of (Z)- and (E)-cyclododecene with N-bromosuccinimide in the presence of water, methanol or acetic acid, are described. In every case,trans-1,2-addition is observed. Whereas hydroxybromination and methoxybromination result in the formation of 2-bromocyclododecanol, and 2-bromo-1-methoxycyclododecane, resp., acetoxybromination gives 1-acetoxy-2-bromocyclododecane in addition to 2,2′-dibromodicyclododecylether.
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Aus der Dissertation zur Promotion A,G. Haufe, Karl-Marx-Universität Leipzig, 1975.
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Haufe, G., Mühlstädt, M. & Graefe, J. Hydroxybromierung, Methoxybromierung und Acetoxybromierung von (Z)- und (E)-Cyclododecen. Monatshefte für Chemie 107, 653–661 (1976). https://doi.org/10.1007/BF00906771
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DOI: https://doi.org/10.1007/BF00906771