Skip to main content
SpringerLink
Log in

Highly sensitive spectrophotometric determination of osmium(VIII) with pyrogallolphthalein and hydrogen peroxide in the presence of Brij 35

  • Short Communications
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Summary

A highly sensitive determination of osmium(VIII) is based on the decolouring reaction with pyrogallolphthalein (gallein) and hydrogen peroxide in the presence of Brij 35. Beer's law was obeyed in the range of 0–0.5 ng of osmium(VIII) per 10 ml and the apparent decomposed absorption coefficient was 2.5×109 l mol−1 cm−1 at 535 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Fujita Y, Mori I, Toyoda M (1992) Anal Sci 8:313–316

    Google Scholar 

  2. Goldstein G, Manning DL, Menis O, Dean JA (1961) Talanta 7:296–306

    Google Scholar 

  3. Kalyanaraman S, Khopkar SM (1975) Anal Chim Acta 78:231–233

    Google Scholar 

  4. Majumdar AK, Bhowal SK (1972) Anal Chim Acta 62:223–226

    Google Scholar 

  5. Faye GH (1965) Anal Chem 37:259–261; 696–701

    Google Scholar 

  6. Röbisch G, Pfendt B (1984) Fresenius Z Anal Chem 318:353–357

    Google Scholar 

  7. Khomnutova EG, Khvorostukhina NA, Rysev AP, Samutenkava IN (1985) J Anal Chem USSR 40:249–253

    Google Scholar 

  8. Ki Z, Xu Q (1989) Yankuang Ceshi 8:179–182; Anal Abstr (1990) 52:11B

    Google Scholar 

  9. Mishura P, Khandual NC (1986) Indian J Chem 28A 902–904

    Google Scholar 

  10. Mori I, Fujita Y, Ikuta K, Nakahashi Y, Kato K, Tamura K, Ohji M (1989) Fresenius Z Anal Chem 334:49–52

    Google Scholar 

  11. Mori I, Fujita Y, Fujita K, Nakahashi Y, Matsuo R, Kato K (1989) Fresenius Z Anal Chem 333:42–45

    Google Scholar 

  12. Muschtakova SP, Kraskova TP, Gumenyuk AP, Romanova EA (1988) Zhur Anal Khim 43:2014–1017; Anal Abstr (1989) 51:7B143

    Google Scholar 

  13. Sanz-Medel A, Alonso JIG (1984) Anal Chim Acta 165:159–169

    Google Scholar 

  14. Medina J, Hernandez F, Marin R, Lopez FJ (1986) Analyst 111:235–237

    Google Scholar 

  15. Wu Quianfen (1985) Talanta 32:507–509

    Google Scholar 

  16. Zaki MTM, El-Atrsh AM, Mahmoud WH, El-Sayed AY (1988) Analyst 113:937–940

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Osaka University of Pharmaceutical Sciences, Matsubara-shi, 580, Osaka, Japan

    Itsuo Mori, Yoshikazu Fujita, Minako Toyoda & Yoko Takeuchi

Authors
  1. Itsuo Mori
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yoshikazu Fujita
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Minako Toyoda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yoko Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Application of xanthene derivatives in analytical chemistry. Part XCIII. Part XCII see ref. [1]

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mori, I., Fujita, Y., Toyoda, M. et al. Highly sensitive spectrophotometric determination of osmium(VIII) with pyrogallolphthalein and hydrogen peroxide in the presence of Brij 35. Fresenius J Anal Chem 344, 292–294 (1992). https://doi.org/10.1007/BF00324993

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00324993

Keywords

Search

Navigation