Abstract
The pore fluids of the sediments collected at the deepest point of Lac Léman (Switzerland) are supersaturated with respect to vivianite and siderite. In the presence of sulphide, the iron solubility is controlled entirely by the amorphous iron sulphides. As the iron (II) becomes dominant, the formation of siderite occurs and evidence of this, in the solid phase, can be obtained by the use of Mössbauer spectroscopy and some sequential chemical extractions. The amount of ‘siderite iron’ decreases from about 10% near the sediment surface to a few percent in the lower levels of the sediment (<10 cm). Evidence for vivianite formation could not be obtained even in the lower layers, despite the precautions taken to avoid oxidation. Although the trace metal behaviour in the solid phase is well correlated with the iron and manganese, availability in the pore fluid is dependent on the adsorption on, or co-precipitation with, finely dispersed colloids, which pass through a 0.45 μm filter. Trace metal concentrations in pore fluid were not directly related to total elemental concentrations in the solid phase, and did not reflect cumulative trends associated with anthropogenic enrichment.
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References
Anthony, R. S., 1977. Iron rich rhythmically laminated sediments in Lake of the Clouds, northeastern Minnesota. Limnol. Oceanogr. 22: 45–54.
Bancroft, G. M., 1973. Mössbauer Spectroscopy. An Introduction for Inorganic Chemists and Geochemists, pp. 189–190. McGraw-Hill, Maidenhead, U.K.
Bergerioux, C. & Haerdi, W., 1980. Co-precipitation of dissolved trace elements. Chem. Analysis 8: 169–173.
Berner, R. A., 1964. Stability fields of iron minerals in anaerobic marine sediments. J. Geol. 72: 826–834.
Bray, J. T., Bricker, O. P. & Troup, B. N., 1973. Phosphate in interstitial waters of anoxic sediments: oxidation effects during sampling procedure. Science 180: 1362–1364.
Carignan, R. & Flett, R. J., 1974. Postdepositional mobility of phosphorus in lake sediments. Limnol. Oceanogr. 26: 361–366.
Coey, J. M. D., Schindler, D. W. & Weber, F., 1974. Iron compounds in lake sediments. Can. J. Earth Sci. 11: 1489–1493.
Coey, J. M. D., 1975. Iron in postglacial lake sediment core: a Mössbauer effect study. Geochim. cosmochim. Acta 39: 401–415.
Davison, W., 1977. The polarographic measurement of O, Fe, Mn and S in hypolimnetic water. Limnol. Oceanogr. 22: 746–753.
Elderfield, H. & Hepworth, A., 1975. Diagenesis, metals and pollution in estuaries. Mar. Poll. Bull. 6: 85–87.
Emerson, S., 1976. Early diagenesis in anaerobic lake sediments: chemical equilibria in interstitial waters. Geochim. cosmochim. Acta 42: 1307–1316.
Förstner, U. & Witmann, G. T. W., 1979. Metal pollution in the Aquatic Environment. Springer-Verlag, Berlin. 486 pp.
Garrels, R. M. & Christ, C. L., 1965. Solutions, Minerals and Equilibria. Harper and Row, New York. 450 pp.
Hubert, P., Martin, E., Meyback, M., Oliver, P. & Siwertz, E., 1969. Aspects hydrologique, géochimique et sédimentologique de la crue exceptionelle de la Dranse du Chalbais du 22 sept. 1968. Arch. Sci. Soc. Phys. (Genève) 22: 581–603.
Inoue, Y. & Munemori, M., 1979. Coprecipitation of mercury(II) with iron(III) hydroxide. Env. Sci. Technol. 13: 443–445.
Jaquet, J. M., Nembrini, G., Garcia, J. & Vernet, J. P., 1982. The Mn cycle in Lac Léman (Switzerland). The role of Metallogenium. ( These proceedings).
Jenne, A. E., 1968. Trace inorganics in water. Adv. Chem. Ser. 73: 337–387.
Jones, B. F. & Bowser, C. J., 1978. The mineralogy and related chemistry of lake sediments. In: Lerman, A. (Ed.) Lakes- Chemistry, Geology, Physics, pp. 179–235. Springer-Verlag, New York.
Krom, M. D. & Sholkowitz, E. R., 1977. Nature and reactions of dissolved organic matter in the interstitial waters of marine sediments. Geochim. cosmochim. Acta 41: 1565–1573.
Manning, P. G., 1977. Mössbauer spectral studies of ferric phosphate interactions in sediments underlaying oxic lake waters. Can. Mineral. 12: 120–123.
Manning, P. G. & Ash, L. A., 1978. Môssbauer spectral studies of Lake Erie Sediments. Can. Mineral. 16: 577–580.
Manning, P. G., Williams, J. D. H., Charlton, M. N., Ash, L. A. & Birchall, T., 1979. Mössbauer spectral studies of the diagenesis of iron in sulphide rich sediment core. Nature 280: 134–135.
Manning, P. G., Jones, W. & Birchall, T., 1980. Mössbauer spectral studies of iron enriched sediments from Hamilton Harbour (Ontario). Can. Mineral. 18: 291–299.
Nembrini, G., Capobianco, J. A., Williams, A. & Viel, M., 1982. Mössbauer evidence for vivianite formation in lago Maggiore sediments. (Submitted to Geochem. cosmochim. Acta).
Perlow, G. J., Potzel, W. & Edginton, D., 1974. Serial study of Lake Michigan sediments by the Fe Mössbauer spectroscopy. J. Phys. (Paris) 35: (Colloq. 6) 547–548.
Potsma, D., 1981. Formation of siderite and vivianite and the pore water composition of a recent bog sediment in Denmark. Chem. Geol. 31: 225–244.
Rapin, F., Davaud, E. & Vernet, J. P., 1978. Etude générale de la pollution des sédiment du Leman. Rapport Comm. int. Protect. Leman. 294–309.
Stumm, W. & Morgan, J. J., 1981. Aquatic Chemistry. An Introduction Emphasizing Chemical Equilibria in Natural Waters, 2nd edn., pp. 310–313. John Wiley, New York.
Suess, E., 1979. Mineral phases formed in anoxic sediments by microbial decomposition of organic matter. Geochim. cosmochim. Acta 43, 339–352.
Swallow, K. C., Hume, D. N. & Morel, F. F., 1980. Sorption of copper and lead by hydrous ferric oxide. Env. Sci. Technol. 14: 1326–1331.
Tessier, A., Campbell, P. G. C. & Bisson, M., 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analyt. Chem. 51: 844–851.
Tessier, A., Campbell, P. G. C. & Bisson, M., 1980. Trace metal speciation in the Yamaska and St. Francois Rivers (Quebec). Can. J. Earth Sci. 17: 90–105.
Troup, B. N., Bricker, O. P. & Bray, J. T., 1974. Oxidation effect on the analysis of iron in the interstitial water of recent anoxic sediments. Nature 249: 237–239.
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Nembrini, G., Capobianco, J.A., Garcia, J., Jacquet, JM. (1982). Interaction between interstitial water and sediment in two cores of Lac Léman, Switzerland. In: Sly, P.G. (eds) Sediment/Freshwater Interaction. Developments in Hydrobiology, vol 9. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-8009-9_36
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DOI: https://doi.org/10.1007/978-94-009-8009-9_36
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