Abstract
Chromite-rich samples from the ultrabasic and basic igneous complex in the Shetland Islands contain exceptionally rich PGE concentrations previously unrecorded in other ophiolite complexes and geochemically similar to those in stratiform complexes. This chapter re-assesses the Shetland complex, with particular emphasis on the chrome spinels and dykes, confirming that it forms the lower part of a Penrose ophiolite assembly. The podiform chromite is shown to have ophiolitic compositions and new electron microprobe analyses from chromite-rich samples indicate that there is nothing unusual about the compositions of the chrome spinels in PGM-rich samples, which have similar compositions to barren samples. The uppermost part of the ophiolite complex consists of a swarm of dykes in gabbro and their geochemistry has boninitic affinities possibly indicating an origin for the complex from a hydrous magma source in a supra-subduction zone (SSZ). The relative roles of primary and secondary fluids in the concentration of the PGE in Shetland are difficult to determine because the chromite-rich lithologies characteristically lie in altered, highly serpentinized zones. Dunites associated with some of the PGE-rich chromite in lenses in the mantle harzburgite have been found to be PGE-rich and significantly these are some of the least altered of the ultramafic rocks. This suggests that the PGE concentrations are not solely related to alteration zones or secondary processes.
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References
Agiorgitis G, Wolf R (1978) Aspects of osmium, ruthenium and iridium contents in some Greek chromites. Chem Geol 23:267–272
Amin MS (1954) Notes on the ultrabasic body of Unst, Shetland Island. Geol Mag 91:399–406
Augé T (1985) Platinum-group-mineral inclusions in ophiolitic chromite from the Vourinos complex, Greece. Can Miner 23:163–171
Ballhaus CG, Stumpfl EF (1985) Occurrence and petrological significance of graphite in the Upper Critical Zone, western Bushveld complex, S Africa. Earth Planet Sci Lett 74:58–68
Cameron WE, Nisbet EG, Dietrich VJ (1979) Boninites, komatiites and ophiolitic basalts. Nature 280:550–553
Coish RA, Hickey R, Frey FA (1982) Rare earth element geochemistry of the Betts Cove ophiolite, Newfoundland: complexities in ophiolite formation. Geochim Cosmochim Acta 46:2117–2134
Conference Participants (1972) Ophiolites Penrose field conference. Geotimes 7:24–25
Constantinides CC, Kingston GA, Fisher PC (1980) The occurrence of platinum group minerals in the chromitites of the Kokkinorotsos chrome mine, Cyprus. In: Panayiotou A (ed) Ophiolites Proc Int Ophiolite Symp Cyprus 1979, Cyprus Ministry of Agriculture and Natural Resources, pp 93–701
Dickey JS Jr (1975) A hypothesis of origin for podiform chromite deposits. Geochim Cosmochim Acta 39:1061–1074
Flinn D (1970) Some aspects of the geochemistry of the metamorphic rocks of Unst and Fetlar, Scotland. Proc Geol Assoc 81:509–527
Flinn D (1985) The Caledonides of Shetland. In Gee DG, Sturt BA (eds) The Caledonide Orogen-Scandinavia and related areas John Wiley pp 1159–1172
Garson MS, Plant JA (1973) Alpine type ultramafic rocks and episodic mountain building in the Scottish Highlands. Nature 242:34–38
Gass IG, Neary CR, Prichard HM, Bartholomew ID (1982) The chromite of the Shetland ophiolite. A re-appraisal in the light of new theory and techniques. A Report for the Commission of European Communities, Milton Keynes, The Open University
Gunn AG, Leake RC, Styles MT, Bateson JH (1985) Platinum-group element mineralisation in the Unst ophiolite, Shetland. Rep Br Geol Surv 73:115
Heddle MF (1879) The geognosy and mineralogy of Scotland, Orkney and Shetland Island of Unst Miner Mag 2:12–35
Hibbert S (1821) Discovery of chromate of iron in Shetland. Trans Soc Lond Encour Arts Manuf Commer 38:23–26
Hitchen CS (1929) Unst and its chromite deposits. Mining Mag 40:18–24
Irvine TN, Keith DW, Todd SG (1983) The J.M. platinum-palladium reef of the Stillwater complex, Montana. II. Origin by double-diffusive convective magma mixing and implications for the Bushveld complex. Econ Geol 78:1287–1334
Johnson CE, Smith CG, Fortey NJ (1980) Geophysical investigation of chromite-bearing ultrabasic rocks in Baltasound-Hagdale area Unst Shetland Islands Rep Inst Geol Sci 35:70
Naldrett AJ, Duke JM (1980) Platinum metals in magmatic sulphide ores. Science 208:1417–1424
Neary CR, Brown MA (1979) Chromites from the Al’Ays complex, Saudi Arabia, and the Semail complex, Oman. In: Al-Shanti AMS (ed) Evolution and mineralization of the Arabian-Nubian Shield. AG Bull. 2:193–205
Neary CR, Prichard HM (1985) Molybdenum mineralisation on Unst, Shetland Isles. Scott J Geol 21:197–204
Neary CR, Prichard HM, Potts PJ (1984) Chromite, platinoids, gold and moly in the Shetlands. Mining Mag 151:559–560
Page NJ, Pallister JS, Brown MA, Smewing JD, Haffty J (1982a) Palladium, platinum, rhodium, iridium and ruthenium in chromite-rich rocks from the Semail ophiolite, Oman. Can Miner 20: 537–548
Page NJ, Cassard D, Haffty J (1982b) Palladium, platinum, rhodium, ruthenium and iridium in chromi-tities from the Massif du Sud and Tiebaghi Massive, New Caledonia. Econ Geol 77:1571–1577
Page NJ, Engin T, Singer DA, Haffty J (1984) Distribution of platinum group elements in the Bati Kef chromite deposit, Guleman-Etazig area, Eastern Turkey. Econ Geol 79:177–184
Pearce JA, Alabaster T, Shelton AW, Searle MP (1981) The Oman ophiolite as a Cretaceous arc-basin complex: evidence and implications. Philos Trans R Soc Lond A Math Phys Sci 300:299–317
Pearce JA, Lippard SJ, Roberts S (1984) Characteristics and tectonic significance of supra-subduction zone ophiolites. In: Kokelaal BP, Howells MF (eds) Marginal basin geology. Geol Soc Spec Publ 16:77–94
Phillips FC (1927) The serpentines and associated rocks and minerals of the Shetland Islands. QJ Geol Soc Lond 83:622–652
Potts PJ (1984) Neutron activation-induced beta-autoradiography as a technique for locating minor phases in thin section: application to rare earth element and platinum-group element mineral analysis. Econ Geol 79:738–747
Potts PJ (1986) Neutron activation induced beta-autoradiography as a technique for locating minor phases in thin section emulsion response characteristics. Mater Sci Forum 7:35–44
Potts PJ, Webb PC, Watson JS (1984) Energy dispersive X-ray fluorescence analysis of silicate rocks for major and trace elements, X-ray spectrum 13:1–15
Prichard HM (1985) The Shetland ophiolite. In: Gee DG, Sturt BA (eds) The Caledonide Orogen-Scandinavia and related areas Wiley, New York, pp 1173–1184
Prichard HM, Neary CR (1981) Chromite in the Shetland Islands ophiolite complex. In: An international symposium on metallogeny of mafic and ultramafic complexes UNESCO Project 169(3):343–360, Athens
Prichard HM, Neary CR (1982) Some observations on the chromite in the Shetland ophiolite complex. Ofioliti 2/3:455–466
Prichard HM, Tarkian M (1986) Platinum group minerals from two PGE-rich localities in the Shetland ophiolite complex. Abstract 14th General Meeting of the International Mineralogical Association California, p 204
Prichard HM, Potts PJ, Neary CR (1981) Platinum group element minerals in the Unst chromite Shetland Isles. Trans Inst Mining Metall (Sect B: Appt Earth Sci) 90:186–188
Prichard HM, Neary CR, Potts PJ (1984) Platinum and gold in the Shetland ophiolite Mining J 303:77
Prichard HM, Neary CR, Potts PJ (1986) Platinum group minerals in the Shetland ophiolite. In: Metallogeny of basic and ultrabasic rocks. (eds) Gallagher MJ, Ixer RA, Neary CR, Prichard HM, The Institution of Mining and Metallurgy, London, pp 395–414
Read HH (1934) The metamorphic geology of Unst in the Shetland Islands. Q J Geol Soc Lond 90:637–688
Rivington JB (1953) Recent chromite exploration in Shetland. Mining Mag 89:329–337
Rothery DA (1983) The base of a sheeted dyke complex, Oman ophiolite: implications for magma chambers at oceanic spreading axes. J Geol Soc 140:287–296
Thayer TP (1960) Some critical differences between Alpine-type and stratiform peridotite-gabbro complexes. Rep Int Geol Cong pt 13, Copenhagen, pp 247–259
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Prichard, H.M., Lord, R.A. (1988). The Shetland Ophiolite: Evidence for a Supra-Subduction Zone Origin and Implications for Platinum-Group Element Mineralization. In: Boissonnas, J., Omenetto, P. (eds) Mineral Deposits within the European Community. Special Publication No. 6 of the Society for Geology Applied to Mineral Deposits, vol 6. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-51858-4_16
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DOI: https://doi.org/10.1007/978-3-642-51858-4_16
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