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Adsorption of Heavy Metal Ions by Immobilized Phytic Acid

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Part of the book series: Applied Biochemistry and Biotechnology ((ABAB,volume 63-65))

Abstract

Phytic acid (myoinositol hexaphosphate) or its calcium salt, phytate, is an important plant constituent. It accounts for up to 85% of total phos­phorus in cereals and legumes. Phytic acid has 12 replaceable protons in the phytic molecule, rendering it the ability to complex with multivalent cations and positively charged proteins. Poly 4-vinyl pyridine (PVP) and other strong-based resins have the ability to adsorb phytic acid. PVP has the highest adsorption capacity of 0.51 phytic acid/resins. The PVP resin was used as the support material for the immobilization of phytic acid. The immobilized phytic acid can adsorb heavy metal ions, such as cad­mium, copper, lead, nickel, and zinc ions, from aqueous solutions. Adsorption isotherms of the selected ions by immobilized phytic acid were conducted in packed-bed column at room temperature. Results from the adsorption tests showed 6.6 mg of Cd2+, 7 mg of Cu2+, 7.2 mg of Ni2+, 7.4 mg of Pb2+, and 7.7 mg of Zn2+ can be adsorbed by each gram of PVP-phytic acid complex. The use of immobilized phytic acid has the potential for removing metal ions from industrial or mining waste water.

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© 1997 Humana Press Inc.

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Tsao, G.T., Zheng, Y., Lu, J., Gong, C.S. (1997). Adsorption of Heavy Metal Ions by Immobilized Phytic Acid. In: Davison, B.H., Wyman, C.E., Finkelstein, M. (eds) Biotechnology for Fuels and Chemicals. Applied Biochemistry and Biotechnology, vol 63-65. Humana Press. https://doi.org/10.1007/978-1-4612-2312-2_65

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  • DOI: https://doi.org/10.1007/978-1-4612-2312-2_65

  • Publisher Name: Humana Press

  • Print ISBN: 978-1-4612-7497-1

  • Online ISBN: 978-1-4612-2312-2

  • eBook Packages: Springer Book Archive

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