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Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture pp 1–51Cite as

Recent Trends in the Polymerization of α-Olefins Catalyzed by Organometallic Complexes of Early Transition Metals

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 133))

Abstract

This review article describes recent progress in the field of homogeneous organometallic catalysts for olefin polymerization and focuses on the metal-carbon bonding character of the transition metal complexes used as catalysts. Most catalysts of this kind are based on metallocene derivatives of Group 4 metals, their catalytic behavior (such as activity and stereospecificity) and the molecular weights of the resulting polymers are surveyed on the basis of the molecular structure of the catalyst precursors. Advanced mechanistic studies on the catalyst systems are also summarized. Some examples of the related polymerization of functionalized olefins are also presented. Not only the Group 4 metal catalysts but also the polymerization catalysts of many other early transition metals and late transition metals are reviewed including our recent study on the mono(cyclopentadienyl)mono(diene) complexes of Group 5 metals.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, 560, Japan

    Kazushi Mashima

  2. Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560, Japan

    Yuushou Nakayama & Akira Nakamura

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  1. Kazushi Mashima
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  2. Yuushou Nakayama
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D. A. Canelas J. M. DeSimone A. Harada E. Ihara K. Mashima A. Nakamura Y. Nakayama H. Yasuda

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Mashima, K., Nakayama, Y., Nakamura, A. (1997). Recent Trends in the Polymerization of α-Olefins Catalyzed by Organometallic Complexes of Early Transition Metals. In: Canelas, D.A., et al. Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture. Advances in Polymer Science, vol 133. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68442-5_1

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