Skip to main content
Log in

Oil spill cleanup from sea water by carbon nanotube sponges

  • Research Article
  • Published:
Frontiers of Materials Science Aims and scope Submit manuscript

Abstract

Oil spills in the sea have caused many serious environmental problems worldwide. In this study, carbon nanotube (CNT) sponges were used to cleanup oil slicks on sea waters. This method was compared with two traditional representative sorbents, including polypropylene fiber fabric and woolen felt. The CNT sponges had a larger oil sorption capacity than the other two sorbents. The maximum oil sorption capacity (Q m) of the CNT sponge was 92.30 g/g, which was 12 to 13.5 times larger than the Q m of the other two sorbents (the Q m of the polypropylene fiber fabric and woolen felt were 7.45 and 6.74 g/g, respectively). In addition, unlike the other two sorbents, the CNT sponge was superhydrophobic and did not adsorb any water during oil spill cleanup. CNT sponges are potentially very useful for cleaning up oil spills from sea water.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bayat A, Aghamiri S F, Moheb A, et al. Oil spill cleanup from sea water by sorbent materials. Chemical Engineering & Technology, 2005, 28(12):1525–1528

    Article  CAS  Google Scholar 

  2. Fay J A. Model of spills and fires from LNG and oil tankers. Journal of Hazardous Materials, 2003, 96(2–3):171–188

    Article  CAS  Google Scholar 

  3. Daling P S, Singsaas I, Reed M, et al. Experiences in dispersant treatment of experimental oil spills. Spill Science & Technology Bulletin, 2002, 7(5–6):201–213

    Article  CAS  Google Scholar 

  4. Ceylan D, Dogu S, Karacik B, et al. Evaluation of butyl rubber as sorbent material for the removal of oil and polycyclic aromatic hydrocarbons from seawater. Environmental Science & Technology, 2009, 43(10):3846–3852

    Article  CAS  Google Scholar 

  5. James I D. Modelling pollution dispersion, the ecosystem and water quality in coastal waters: a review. Environmental Modelling & Software, 2002, 17(4):363–385

    Article  Google Scholar 

  6. Zheng L, Yapa P D. Modeling gas dissolution in deepwater oil/gas spills. Journal of Marine Systems, 2002, 31(4):299–309

    Article  Google Scholar 

  7. Teas C, Kalligeros S, Zanikos F, et al. Investigation of the effectiveness of absorbent materials in oil spills clean up. Desalination, 2001, 140(3):259–264

    Article  CAS  Google Scholar 

  8. Mauter M S, Elimelech M. Environmental applications of carbonbased nanomaterials. Environmental Science & Technology, 2008, 42(16):5843–5859

    Article  CAS  Google Scholar 

  9. Deschamps G, Caruel H, Borredon M-E, et al. Oil removal from water by selective sorption on hydrophobic cotton fibers. 1. Study of sorption properties and comparison with other cotton fiberbased sorbents. Environmental Science & Technology, 2003, 37(5):1013–1015

    Article  CAS  Google Scholar 

  10. Deschamps G, Caruel H, Borredon M-E, et al. Oil removal from water by sorption on hydrophobic cotton fibers. 2. Study of sorption properties in dynamic mode. Environmental Science & Technology, 2003, 37(21):5034–5039

    Article  CAS  Google Scholar 

  11. Radetić M M, Jocić D M, Jovančić P M, et al. Recycled woolbased nonwoven material as an oil sorbent. Environmental Science & Technology, 2003, 37(5):1008–1012

    Article  Google Scholar 

  12. Toyoda M, Inagaki M. Heavy oil sorption using exfoliated graphite: New application of exfoliated graphite to protect heavy oil pollution. Carbon, 2000, 38(2):199–210

    Article  CAS  Google Scholar 

  13. Wong K, Stewart H O. Oil spill boom design for waves. Spill Science & Technology Bulletin, 2003, 8(5–6):543–548

    Article  Google Scholar 

  14. Prince R C. Bioremediation of marine oil spills. Trends in Biotechnology, 1997, 15(5):158–160

    Article  CAS  Google Scholar 

  15. Gui X C, Wei J Q, Wang K L, et al. Carbon nanotube sponges. Advanced Materials, 2010, 22(5):617–621

    Article  CAS  Google Scholar 

  16. ASTM D 1141. Annual Book of ASTM Standards, Vol. 11.02. Philadephia, PA: American Society of Testing and Materials, 2003

    Google Scholar 

  17. Bastani D, Safekordi A A, Alihosseini A, et al. Study of oil sorption by expanded perlite at 298.15 K. Separation and Purification Technology, 2006, 52(2):295–300

    Article  CAS  Google Scholar 

  18. Yaneva Z, Koumanova B. Comparative modelling of mono- and dinitrophenols sorption on yellow bentonite from aqueous solutions. Journal of Colloid and Interface Science, 2006, 293(2):303–311

    Article  CAS  Google Scholar 

  19. Rudzinski W, Plazinski W. Kinetics of solute adsorption at solid/aqueous interfaces: searching for the theoretical background of the modified pseudo-first-order kinetic equation. Langmuir, 2008, 24(10):5393–5399

    Article  CAS  Google Scholar 

  20. Ho Y S, Mckay G. Pseudo-second order model for sorption processes. Process Biochemistry, 1999, 34(5):451–465

    Article  CAS  Google Scholar 

  21. Kumar K V. Pseudo-second order models for the adsorption of safranin onto activated carbon: Comparison of linear and nonlinear regression methods. Journal of Hazardous Materials, 2007, 142(1–2):564–567

    Article  CAS  Google Scholar 

  22. Kumar K V, Porkodi K. Modelling the solid-liquid adsorption processes using artificial neural networks trained by pseudo second order kinetics. Chemical Engineering Journal, 2009, 148(1):20–25

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to An-Yuan Cao or Hong-Wei Zhu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhu, K., Shang, YY., Sun, PZ. et al. Oil spill cleanup from sea water by carbon nanotube sponges. Front. Mater. Sci. 7, 170–176 (2013). https://doi.org/10.1007/s11706-013-0200-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11706-013-0200-1

Keywords

Navigation