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Reactive Atmospheric Plasma Spraying of AlN Coatings: Influence of Aluminum Feedstock Particle Size

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Abstract

Feedstock powder characteristics (size distribution, morphology, shape, specific mass, and injection rate) are considered to be one of the key factors in controlling plasma-sprayed coatings microstructure and properties. The influence of feedstock powder characteristics to control the reaction and coatings microstructure in reactive plasma spraying process (RPS) is still unclear. This study, investigated the influence of feedstock particle size in RPS of aluminum nitride (AlN) coatings, through plasma nitriding of aluminum (Al) feedstock powders. It was possible to fabricate AlN-based coatings through plasma nitriding of all kinds of Al powders in atmospheric plasma spray (APS) process. The nitriding ratio was improved with decreasing the particle size of feedstock powder, due to improving the nitriding reaction during flight. However, decreasing the particle size of feedstock powder suppressed the coatings thickness. Due to the loss of the powder during the injection, the excessive vaporization of fine Al particles and the completing nitriding reaction of some fine Al particles during flight. The feedstock particle size directly affects on the nitriding, melting, flowability, and the vaporization behaviors of Al powders during spraying. It concluded that using smaller particle size powders is useful for improving the nitriding ratio and not suitable for fabrication thick AlN coatings in reactive plasma spray process. To fabricate thick AlN coatings through RPS, enhancing the nitriding reaction of Al powders with large particle size during spraying is required.

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Acknowledgments

This work was supported by MEXT KAKENHI (21760583). M. Shahien would like to thank NGK foundation in Aichi, Japan for the financial support.

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  1. Toyohashi University of Technology, 1-1, Tempaku-cho, Toyohashi, 441-8580, Japan

    Mohammed Shahien, Motohiro Yamada, Toshiaki Yasui & Masahiro Fukumoto

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  1. Mohammed Shahien
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Correspondence to Mohammed Shahien.

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Shahien, M., Yamada, M., Yasui, T. et al. Reactive Atmospheric Plasma Spraying of AlN Coatings: Influence of Aluminum Feedstock Particle Size. J Therm Spray Tech 20, 580–589 (2011). https://doi.org/10.1007/s11666-010-9582-0

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