It was shown that porous coordination polymers (PCPs) of 3d metals containing chiral centers in fragments of deprotonated (S)-lactic and (R)-aspartic acid or trimesoyl-(S)-alanine are characterized by different values of sorption capacity with respect to the individual optical isomers of 2-butanol upon sorption of such substrates from the gas phase. The difference between the sorption capacity values with respect to the (R) and (S) isomers of 2-butanol correlates with the value of the enantiomeric excess achieved upon separation of the alcohol racemate on the respective PCP by column chromatography.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 1, pp. 41-48, January-February, 2015.
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Satska, Y.A., Komarova, N.P., Gavrilenko, K.S. et al. Sorption and Separation of Optical Isomers of 2-Butanol by Chiral Porous Coordination Polymers. Theor Exp Chem 51, 45–53 (2015). https://doi.org/10.1007/s11237-015-9396-8
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DOI: https://doi.org/10.1007/s11237-015-9396-8