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Photochemical arene exchange in the iron dicarbollide complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+

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Abstract

Visible light irradiation of the dicarbollide complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ (2a) in the presence of the benzene derivatives in CH2Cl2/MeNO2 resulted in cations [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6R6)]+ (2b-g; arene is anisole (b), toluene (c), m-xylene (d), mesitylene (e), durene (f), and hexamethylbenzene (g)) due to the arene exchange. The structures of [2g]PF6 and related tricarbollide complex [(η-1-ButNH-1,7,9-C3B8H10)Fe-(η-C6H6)]PF6 (1) were confirmed by X-ray diffraction analysis. The nature of bonding in cations 1, 2a, and [CpFe(η-C6H6)]+ was analyzed by an energy decomposition analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, M. M. Vinogradov, Z. A. Starikova & A. R. Kudinov

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  1. D. A. Loginov
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  2. M. M. Vinogradov
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  3. Z. A. Starikova
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  4. A. R. Kudinov
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Correspondence to A. R. Kudinov.

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Dedicated to blessed memory of P. V. Petrovskii who contributed considerably to the development of organometallic chemistry.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1262–1267, May, 2013.

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Loginov, D.A., Vinogradov, M.M., Starikova, Z.A. et al. Photochemical arene exchange in the iron dicarbollide complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ . Russ Chem Bull 62, 1262–1267 (2013). https://doi.org/10.1007/s11172-013-0174-2

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  • DOI: https://doi.org/10.1007/s11172-013-0174-2

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