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Furazan-containing bromoarenes in the Suzuki-Miyaura reaction

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Abstract

The palladium-catalyzed cross-coupling reactions of 3-[bromo(het)aryl]furazans and bromobenzofurazans with arylboronic acids afford target biaryls in good yields. 3-Bromo-4-phenylfurazan containing a bromine atom in the furazan ring undergoes decomposition under the reaction conditions.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Vasil’ev, M. I. Struchkova & A. B. Sheremetev

  2. Kazan State Technological University, 68 ul. Karla Marksa, 420015, Kazan, Russian Federation

    F. S. Levinson & R. V. Varganov

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko

Authors
  1. A. A. Vasil’ev
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  2. M. I. Struchkova
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  3. A. B. Sheremetev
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  4. F. S. Levinson
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  5. R. V. Varganov
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  6. K. A. Lyssenko
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Corresponding authors

Correspondence to A. A. Vasil’ev or A. B. Sheremetev.

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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2262–2269, November, 2011.

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Vasil’ev, A.A., Struchkova, M.I., Sheremetev, A.B. et al. Furazan-containing bromoarenes in the Suzuki-Miyaura reaction. Russ Chem Bull 60, 2306–2314 (2011). https://doi.org/10.1007/s11172-011-0353-y

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  • DOI: https://doi.org/10.1007/s11172-011-0353-y

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