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Replacement of carboxylate bridges in polynuclear nickel pivalates with 2-hydroxy-6-methylpyridine anions

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Abstract

The reaction of 2-hydroxy-6-methylpyridine (HL, 1) with nonanuclear nickel trimethyl-acetate Ni9(OH)6(OOCCMe3)12(HOOCCMe3)4 (2) in MeCN with a ratio M: L = 1: 1 under mild conditions (20 °C, 15 min) led to degradation of the metal core to form the hexanuclear complex (HL)2(µ 2-HL)2Ni6(µ3-OH)2(µ2-H2O)2(µ-OOCCMe3)8(η-OOCCMe3)2 (3). Further heating of 3 in acetonitrile at 80 °C for 4 h afforded the (HL)Ni6(µ 3-OH)(µ3,η2-L)3(µ,η2-L)(µ3-L)(µ 3-OOCCMe3)(µ-OOCCMe3)4(η2-OOCCMe3) complex. The reaction with the use of a 2: 1 THF-EtOH mixture instead of acetonitrile at 50 °C gave the decanuclear complex [Ni10(µ 3-O)2(µ3-OH)4(µ-OOCCMe3)6(µ3,η 2-L)6(EtOH)6](H2O)2, which is also produced from compounds 1 and 2 in ethanol. The structures of the resulting complexes were established by X-ray diffraction.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. E. Nikiforova, A. A. Sidorov, G. G. Aleksandrov & I. L. Eremenko

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    V. N. Ikorskii

  3. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation

    I. V. Smolyaninov & A. O. Okhlobystin

  4. Southern Scientific Center, Russian Academy of Sciences, 4 prosp. Chekhova, 344006, Rostov-on-Don, Russian Federation

    N. T. Berberova

Authors
  1. M. E. Nikiforova
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  2. A. A. Sidorov
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  3. G. G. Aleksandrov
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  4. V. N. Ikorskii
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  5. I. V. Smolyaninov
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  6. A. O. Okhlobystin
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  7. N. T. Berberova
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  8. I. L. Eremenko
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Correspondence to A. A. Sidorov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 908–917, May, 2007.

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Nikiforova, M.E., Sidorov, A.A., Aleksandrov, G.G. et al. Replacement of carboxylate bridges in polynuclear nickel pivalates with 2-hydroxy-6-methylpyridine anions. Russ Chem Bull 56, 943–952 (2007). https://doi.org/10.1007/s11172-007-0143-8

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  • DOI: https://doi.org/10.1007/s11172-007-0143-8

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