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Schiff’s base derived from the pharmaceutical drug Dapsone (DS) as a new and effective corrosion inhibitor for mild steel in hydrochloric acid

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Abstract

The inhibition ability of Dapsone’s Schiff’s base with salicylaldehyde (1:2) for mild steel corrosion in 1 M HCl solution at 308 K was studied by means of potentiodynamic polarization, electrochemical impedance spectroscopy techniques, and gravimetric analysis. Results showed that Dapsone salicylaldehyde performed well as a good inhibitor for mild steel in 1 M HCl solution with maximum inhibition efficiency of 95 % at 500 ppm. The adsorption isotherm of the inhibitor followed the Langmuir adsorption. The value of free energy of adsorption showed that it is a spontaneous process and followed typical physical adsorption.

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Authors and Affiliations

  1. Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, 221005, India

    Ambrish Singh, J. N. Avyaya & M. A. Quraishi

  2. Department of Chemistry, School of Mathematical and Physical Sciences, North-West University, Mafikeng Campus, Private Bag X2046, Mmabatho, 2735, South Africa

    Eno. E. Ebenso

Authors
  1. Ambrish Singh
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  2. J. N. Avyaya
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  3. Eno. E. Ebenso
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  4. M. A. Quraishi
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Correspondence to Eno. E. Ebenso.

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Singh, A., Avyaya, J.N., Ebenso, E.E. et al. Schiff’s base derived from the pharmaceutical drug Dapsone (DS) as a new and effective corrosion inhibitor for mild steel in hydrochloric acid. Res Chem Intermed 39, 537–551 (2013). https://doi.org/10.1007/s11164-012-0577-y

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  • DOI: https://doi.org/10.1007/s11164-012-0577-y

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