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Structural and phase changes of iron substrate upon pulse laser deposition of MoSe x solid lubricating coatings

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Metal Science and Heat Treatment Aims and scope

The effect of the conditions of pulse laser deposition of MoSe x thin-film coatings on the structural and phase state of surface layer on an iron substrate and on the distribution of elements over the thickness of the coatingsubstrate interface is investigated. Model multilayer test pieces bearing a thin film of 57Fe are studied. The speed distributions of single- and double-charge ions due to pulse laser irradiation of a MoSe2 target are measured and used for mathematical modeling of the motion of laser plasma to the surface of the substrate in a pulse electric field. The energy distributions of the incident ions are computed as a function of the time of the action of the high-voltage pulse following the laser pulse and used to explain the experimentally determined effects.

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References

  1. Yu. A. Bykovskii, V. N. Nevolin, and V. Yu. Fominskii, Ion and Laser Implantation of Metallic Materials [in Russian], Énergoatomizdat, Moscow (1991), 240 p.

  2. P. V. Bykov, V. L. Vorob’ev, V. Ya. Bayankin, and S. N. Korshunov, “Effect of the rate of doing in irradiation with manganese ions on the composition of layers and mechanical properties of carbon steel,” Metalloved. Term. Obrab. Met., No. 6, 48–50 (2011).

  3. S. N. Grigor’ev, A. S. Metel, and S. V. Fedorov, “Modification of structure and properties of high-speed steel by combined vacuum-plasma treatment,” Metalloved. Term. Obrab. Met., No. 1, 9–14 (2012).

  4. S. N. Grigoriev, Yu. A. Melnik, and A. S. Metel, “Broad fast neutral molecule beam sources for industrial-scale beam-assisted deposition,” Surf. Coat. Technol., No. 1 – 2, 44–49 (2002).

    Google Scholar 

  5. V. N. Nevolin, V. Yu. Fominskii, R. I. Romanov, and G. A. Kiselev, “Tribological properties of diamond-like carbon coatings formed on steel by ion-assisted deposition from pulse laser plasma,” Uproch. Tekhnol. Pokryt., No. 6, 34–40 (2006).

    Google Scholar 

  6. S. N. Grigor’ev, “Recent vacuum-plasma facilities and technologies of combined hardening of tools and machine parts,” Tekhnol. Mashinostr., No. 3, 20–26 (2004).

  7. A. Anders (ed.), Handbook of Plasma Immersion Ion Implantation and Deposition, New York (200), 282 p.

  8. O. V. Sobol’, A. A. Andreev, S. N. Grigor’ev, et al., “Vacuumarc multilayer nanostructured TiN/Ti coatings: structure, stress state, properties,” Metalloved. Term. Obrab. Met., No. 1, 28–33 (2012).

  9. E. V. Smolentsev and S. N. Grigor’ev, “Methodology of design of combined methods of treatment with application of electric field,” Fund. Prikl. Prob. Tekh. Tekhnol., No. 2, 93–100 (2011).

  10. V. Yu. Fominski, A. M. Markeev, and V. N. Nevolin, “Pulsed ion beams for modification of metal surface properties,” Vacuum, 42(1/2), 73–74 (1991).

    Article  Google Scholar 

  11. V. Yu. Fominski, V. N. Nevolin, R. I. Romanov, and I. Smurov, “Ion-assisted deposition of MoSe x films from laser-generated plume under pulsed electric field,” J. Appl. Phys., 89(2), 1449–1457 (2001).

    Article  CAS  Google Scholar 

  12. J. S. Zabinski, J. J. Hu, J. E. Bultman, N. A. Pierce, and A. A. Voevodin, “Stoichiometry and characterization of aluminum oxynitride film grown by ion-beam-assisted pulsed laser deposition,” Thin Solid Films, 516, 6215–6219 (2008).

    Article  CAS  Google Scholar 

  13. D. V. Shtansky, T. A. Lobova, V. Yu. Fominski, et al., “Structure and wear behavior of WSe x , WSe x /TiN, WSe x /TiCN and WSe x /TiSiN coatings,” Surf. Coat. Technol., 183(2–3), 328–336 (2004).

    Article  CAS  Google Scholar 

  14. R. S. Bhattacharya, A. K. Rai, and A. Erdemir, “High-energy (MeV) ion beam modification of sputtered MoS2 coatings on sapphire,” Nucl. Instr. Meth. Phys. Res. B, 59/60, 788–792 (1991).

    Article  Google Scholar 

  15. K. J. Wahl, D. N. Dunn, and I. L. Singer, “Effects of ion implantation on microstructure, endurance and wear behavior of IBAD MoS2,” Wear, 237, 1–11 (2000).

    Article  CAS  Google Scholar 

  16. V. N. Nevolin, V. Yu. Fominskii, A. G. Gnedovets, and R. I. Romanov, “Study and simulation of growth of MoSe x solid lubricating coatings under pulsed laser deposition,” Zh. Teor. Fiz., 79(1), 118–124 (2009).

    Google Scholar 

  17. M. Mayer, SIMNRA User’s Guide, Rep. IPP 9/113, Max-Planck-Institut für Plasmaphysik, Garching, Germany (1997).

  18. V. Yu. Fominski, R. I. Romanov, A. G. Gnedovets, and V. N. Nevolin, “About the mechanism of formation of chemical composition of thin-film layers from dichalcogenides of transition metals under pulsed laser deposition,” Zh. Teor. Fiz., 80(10), 120–128 (2010).

    Google Scholar 

  19. C. K. Birdsall and A. B. Langdon, Plasma via Computer Simulation, IOP Publ., Bristol (1991), 400 p.

  20. V. N. Nevolin, V. Yu. Fominskii, A. G. Gnedovets, and V. E. Koshmanov, “Experimental studies and simulation of ion implantation from pulse laser plasma in pulse electric fields,” Zh. Teor. Fiz., 75(6), 32–37 (2005).

    Google Scholar 

  21. V. N. Nevolin, V. Yu. Fominskii, A. G. Gnedovets, and R. I. Romanov, “Special features of pulsed laser deposition of thin-film coatings with the use of anti-drip screen,” Zh. Teor. Fiz., 79(11), 120–127 (2009).

    Google Scholar 

  22. C. E. M. Campos, V. Drago, J. C. Lima, et al., “Mössbauer and magnetization studies of Fe25Se75 iron selenides produced by mechanical alloying,” J. Magn. Magn. Mater., 269, 6–14 (2004).

    Article  CAS  Google Scholar 

  23. R. Joshee, D. M. Phase, S. V. Ghaisas, et al., “Conversion electron Mössbauer spectroscopy study of ion-beam mixing at Fe – Mo interface,” J. Appl. Phys., 59(2), 388–394 (1986).

    Article  CAS  Google Scholar 

  24. E. Ibe, “Picosecond diffusion in a thermal spike during ion mixing,” Nucl. Instr. Meth. Phys. Res. B, 39, 148–152 (1989).

    Article  Google Scholar 

  25. V. Yu. Fominski, S. N. Grigor’ev, R. I. Romanov, and V. N. Nevolin, “Effect of conditions of pulsed laser deposition on tribological properties of thin-film nanostructured coatings based on molybdenum diselenide and carbon,” Zh. Teor. Fiz., 82(4), 96–104 (2012).

    Google Scholar 

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Authors and Affiliations

  1. Moscow State Technological University “STANKIN”, Moscow, Russia

    S. N. Grigor’ev & R. I. Romanov

  2. National Research Nuclear University “MIFI”, Moscow, Russia

    V. Yu. Fominskii

  3. A. A. Baikov Institute for Metallurgy and Materials Science of the Russian Academy of Sciences, Moscow, Russia

    A. G. Gnedovets

Authors
  1. S. N. Grigor’ev
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  2. V. Yu. Fominskii
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  3. A. G. Gnedovets
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  4. R. I. Romanov
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Correspondence to V. Yu. Fominskii.

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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 3, pp. 34 – 41, March, 2013.

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Grigor’ev, S.N., Fominskii, V.Y., Gnedovets, A.G. et al. Structural and phase changes of iron substrate upon pulse laser deposition of MoSe x solid lubricating coatings. Met Sci Heat Treat 55, 150–156 (2013). https://doi.org/10.1007/s11041-013-9597-5

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  • DOI: https://doi.org/10.1007/s11041-013-9597-5

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