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Liquid–liquid extraction of scandium with nalidixic acid in dichloromethane

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Abstract

The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III), Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1–7 with 0.1 mol dm−3 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is possible at pH 3.4–4. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride, citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping stages for the extraction of Sc(III).

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Acknowledgment

Yasar Arfat Abbasi one of the authors is highly grateful to HEC of Pakistan for awarding fellowship for Ph D.

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Authors and Affiliations

  1. Department of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad, AJK, Pakistan

    Yasar Arafat Abbasi & Muhammad Haleem Khan

  2. Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan

    Akbar Ali & Muhammad Mufazzal Saeed

  3. Central Analytical Facility Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan

    Kashif Naeem

Authors
  1. Yasar Arafat Abbasi
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  2. Akbar Ali
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  3. Muhammad Haleem Khan
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  4. Muhammad Mufazzal Saeed
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  5. Kashif Naeem
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Correspondence to Akbar Ali.

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Abbasi, Y.A., Ali, A., Khan, M.H. et al. Liquid–liquid extraction of scandium with nalidixic acid in dichloromethane. J Radioanal Nucl Chem 292, 277–283 (2012). https://doi.org/10.1007/s10967-011-1427-x

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  • DOI: https://doi.org/10.1007/s10967-011-1427-x

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