Skip to main content
Log in

Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Zinc di-(4-chlorphenylthioacetate) dihydrate (4-ClC6H4SCH2COO)2Zn·2H2O (ZTD) is obtained in the reaction of protatrane 4-chlorphenylthioacetate 4-ClC6H4SCH2COO 2s- ·N+H(CH2CH2OH)3 with zinc dichloride (ZnCl2) in aqueous alcohol. X-ray diffraction is used to study the crystal structure of ZTD and compare it with related compounds. All intermolecular O…O contacts of the neighboring zinc polyhedra are short in ZTD molecules. Apparently, the short intermolecular O…O contacts cause distortions of the octahedral environment of the zinc atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. N. Mirskova, G. G. Levkovskaya, R. G. Mirskov, and M. G. Voronkov, Zh. Org. Khim., 44, No. 10, 1501 (2008).

    Google Scholar 

  2. S. N. Adamovich, G. A. Kuznetsova, T. V. Kashik, et al., ibid., 78, No. 9, 1523.

  3. S. N. Adamovich, T. V. Kashik, N. N. Chipanina, et al., Zh. Prikl. Khim., 82, No. 5, 808 (2009).

    Google Scholar 

  4. M. C. Burla, R. Caliandro, B. Carrozzini, et at., J. Appl. Crystallogr., 37, 258–264 (2004). Web site: http://www.ic.cnr.it/

    Article  CAS  Google Scholar 

  5. Wing-Hong Chan, T. C. W. Mak, Wai-Hig Yip, et.al., Polyhedron, 6, No. 5, 881–889 (1987).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to É. A. Zelbst.

Additional information

Original Russian Text Copyright © 2010 by M. G. Voronkov, V. S. Fundamenskii, É. A. Zelbst, A. A. Kashaev, A. N. Mirskova, and S. N. Adamovich

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 4, pp. 816–818, July–August, 2010

Rights and permissions

Reprints and permissions

About this article

Cite this article

Voronkov, M.G., Fundamenskii, V.S., Zelbst, É.A. et al. Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate. J Struct Chem 51, 790–792 (2010). https://doi.org/10.1007/s10947-010-0119-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-010-0119-7

Key words

Navigation