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A simple method to synthesize graphitic mesoporous carbon materials with different structures

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Abstract

Graphitic mesoporous carbon materials with different structure were synthesized by reversed replication method. SBA-15 was used as hard template and the synthesized aromatic polymers with different polymerization degree as the carbon sources. Adopting the impregnation method, the carbon source was assembled into the pore of the SBA-15. The silica/aromatic polymers system was carbonized under N2 atmosphere (high polymerization degree aromatic polymers) and vacuum (low polymerization degree aromatic polymers) to produce the graphitic mesoporous carbon materials with structure of CMK-3 and CMK-5, respectively. It is a easy way to synthesize the graphitic mesoporous carbon materials, especial for the CMK-5 structure. The porous structure and composition of these carbon materials were characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman spectrometry, and N2 adsorption–desorption measurements.

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Acknowledgments

Financial support for this study was provided by the National Native Science Foundation of China (21171045, 21101046), Doctoral Initiation Fund of Harbin Normal University (20102329110002), Foundation of Harbin Educational Committee (12521164), Program for Scientific and Technological Innovation team Construction in Universities of Heilongjiang province (2011TD010), Fundamental Research Funds for the Central Universities of China, cutting-edge science and interdisciplinary innovation projects of Jilin University (201103024), Innovation Project of Jilin University Young Teachers.

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Authors and Affiliations

  1. Schcool of Material Science and Engineering, Jilin University, Changchun, 130022, People’s Republic of China

    Qian Gao & Weitao Zheng

  2. State Key Laboratory of Photoelectric Band Gap Materials, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, People’s Republic of China

    Fengyu Qu & Huiming Lin

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  1. Qian Gao
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  2. Fengyu Qu
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  3. Weitao Zheng
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  4. Huiming Lin
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Correspondence to Huiming Lin.

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Gao, Q., Qu, F., Zheng, W. et al. A simple method to synthesize graphitic mesoporous carbon materials with different structures. J Porous Mater 20, 983–988 (2013). https://doi.org/10.1007/s10934-013-9677-3

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  • DOI: https://doi.org/10.1007/s10934-013-9677-3

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