Abstract
(BETS)2[RuX5NO] (X=Cl, Br) exhibit an identical 2:1 stoichiometry. However, while the chlorine derivative shows an insulating behavior, the bromine behaves as a semiconductor with very small activation energy (0.03 eV). The different electrical behaviors are analyzed through the use of a detailed study of structural data and analysis of Raman spectra
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Valade, L., Malfant, I., Glaria, A. et al. (BETS)2[RuX5NO] (X=Cl, Br): an explanation of different conductive properties through structural and spectroscopic studies. J Low Temp Phys 142, 445–448 (2006). https://doi.org/10.1007/BF02679541
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DOI: https://doi.org/10.1007/BF02679541