Abstract
Oxidative stability of products produced as potential margarine basestock from soybean oil and methyl stearate by a novel chemical regioselective interesterification was evaluated. The oxidative stability of the products was evaluated by peroxide formation and volatile analysis during storage in the dark with oxygen at 60°C for 72 h. The product obtained by regioselective interesterification resulted in the lowest peroxide formation and volatile concentration sample in comparison with soybean oil and the randomized product of the regioselective interesterified product. Regioselective interesterification of soybean oil with methyl stearate produced a product with increased oxidative stability.
Similar content being viewed by others
References
Dutton, H.J., C.R. Lancaster, C.D. Evans and J.C. Cowan,J. Am. Oil Chem. Soc. 28:115 (1951).
Evans, C.D., H.A. Moser, D.G. McConnell, J.C. Cowan, J.L. Carter and F.I. Collins, Ibid.736 (1965).
Frankel, E.N., inFlavor Chemistry of Fats and Oils, edited by D.B. Min and T.H. Smouse, American Oil Chemists’ Society, Champaign, 1985, p. 1.
Frankel, E.N.,J. Sci. Food Agric. 54:495 (1991).
Ulrich, F., and W. Grosch,Fat Sci. Technol. 90:332 (1988).
Warner, K., E.N. Frankel and T.L. Mounts,J. Am. Oil Chem. Soc. 66:558 (1989).
Chow, C.K., inFatty Acids in Foods and Their Health Implications, edited by C.K. Chow, Marcel Dekker, Inc., New York, 1992, p. 689.
Warner, K., and E.N. Frankel,J. Am. Oil Chem. Soc. 64:213 (1987).
Mistry, B.S., and D.B. Min,J. Food Sci. 52:786 (1987).
Mistry, B.S., and D.B. Min, Ibid.:831 (1987).
Lee, E.C., and D.B. Min, Ibid.1894 (1988).
Lee, S.W., and D.B. Min,J. Agric. Food Chem. 38:1630 (1990).
Emanuel, N.M., and Y.N. Lyaskovskaya, inThe Inhibition of Fat Oxidation Processes, Pergamon Press, Oxford, 1967, p. 246.
Raghuveer, K.G., and E.G. Hammond,J. Am. Oil Chem. Soc. 44:239 (1967).
Neff, W.E., E.N. Frankel and K. Miyashita,Lipids 25:33 (1990).
Frankel, E.N., W.E. Neff and K. Miyashita, Ibid.40 (1990).
Miyashita, K., E.N. Frankel, W.E. Neff and R.A. Awl, Ibid.48 (1990).
Frankel, E.N., E. Selke, W.E. Neff and K. Miyashita, Ibid.442 (1992).
Cosgrove, J.P., D.F. Church and W.A. Pryor, Ibid.299 (1987).
Neff, W.E., E. Selke, T.L. Mounts, W. Rinsch, E.N. Frankel and M.A.M. Zeitoun,J. Am. Oil Chem. 69:111 (1992).
Hoffmann, G., inThe Chemistry and Technology of Edible Oils and Fats and Their High Fat Products, Academic Press, London, 1989, p. 203.
Mounts, T.L., inFat Production and Consumption, edited by C. Galli and E. Fedeli, Plenum Press, New York, 1987, p. 201.
Snyder, J.M., E.N. Frankel and K. Warner,J. Am. Oil Chem. Soc. 63:1055 (1986).
Warner, K., E.N. Frankel, J.M. Snyder and W.L. Porter,J. Food Sci. 51:703 (1986).
Frankel, E.N., K. Warner and K.J. Moulton Sr.,J. Am. Oil Chem. Soc. 62:1354 (1985).
Warner, K., T.L. Mounts and W.F. Kwolek, Ibid.:1483 (1985).
Miller, K.L.,Cereal Food World 38:478 (1993).
Emken, E.A.,Ann. Rev. Nutr. 4:339 (1984).
Emken, E.A., inHealth Effects of Dietary Fatty Acids, edited by G. Nelson, American Oil Chemists’ Society, Champaign, 1991, p. 245.
Emken, E.A.,Nutrition & the M.D. 17:1 (1991).
Wood, R., inFatty Acids in Foods and Their Health Implications, edited by C.K. Chow, Marcel Dekker, Inc., New York, 1992, p. 663.
Hunter, J.E.,, p. 857.
Hustedt, H.H.,J. Am. Oil Chem. Soc. 53:390 (1976).
Young, F.V.K., Ibid.378 (1985).
Wiedermann, L.H., Ibid.823 (1978).
Sonntag, N.O.V., inBailey’s Industrial Oil and Fat Products, Vol. II, 4th edn., edited by D. Swern, John Wiley and Sons, New York, 1982, p. 147.
Going, L.H.,J. Am. Oil Chem. Soc. 44:414A (1967).
Chobanov, D., and R. Chobanova, Ibid.47 (1977).
Chang, M.K., Ibid.832 (1990).
Macrae, A.R.,Ibid. 60:243A (1983).
Bloomer, S., P. Adlercreutz and B. Mattiasson, Ibid.519 (1990).
Konishi, H., W.E. Neff and T.L. Mounts, Ibid.411 (1993).
List, G.R., E.A. Emken, W.F. Kwolek, T.D. Simpson and H.J. Dutton, Ibid.408 (1977).
Neff, W.E., M.A.M. Zeitoun and D. Weisleder,J. Chromatogr. 589:353 (1992).
Konishi, H., W.E. Neff and T.L. Mounts, Ibid.237 (1993).
Author information
Authors and Affiliations
About this article
Cite this article
Konishi, H., Neff, W.E. & Mounts, T.L. Oxidative stability of soybean oil products obtained by regioselective chemical interesterification. J Am Oil Chem Soc 72, 1393–1398 (1995). https://doi.org/10.1007/BF02546217
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02546217