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Vibrational spectra of the water of crystallization in monocrystals of NiSO4 · 7H2O, NiSO4 · 6H2O, CaSO4 · 2H2O near the fundamental of the O-H valence vibration

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Summary

  1. 1.

    The infrared absorption spectra in the region of the fundamental O−H frequency are reported for crystals of NiSO4·7H2O, NiSO4·6H2O, CaSO4·2H2O from 50 to 15μm thick.

  2. 2.

    The peaks for NiSO4·6H2O and NiSO4·7H2O are displaced about 300 cm−1 to the long-wave side of the peak for CaSO4·2H2O. The hydrates of NiSO4 gives bands much broader than the band given by gypsum.

  3. 3.

    The relation between the O−H frequencies and between the bands widths are explained on the assumption that the energies of the OH2...OSO3 −2 hydrogen bonds depend not only on the H2O... OSO3 −2, distance but also on the Me2+ cation.

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Authors and Affiliations

  1. A. A. Zhdanov State University, Leningrad

    S. N. Andreev, S. A. Shchukarev & T. G. Balicheva

Authors
  1. S. N. Andreev
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  2. S. A. Shchukarev
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  3. T. G. Balicheva
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Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 1, No. 2, pp. 183–188, July–August, 1960

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Andreev, S.N., Shchukarev, S.A. & Balicheva, T.G. Vibrational spectra of the water of crystallization in monocrystals of NiSO4 · 7H2O, NiSO4 · 6H2O, CaSO4 · 2H2O near the fundamental of the O-H valence vibration. J Struct Chem 1, 168–172 (1960). https://doi.org/10.1007/BF00738935

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  • DOI: https://doi.org/10.1007/BF00738935

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